about
A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (·NO(g)) with a Ferric-Superoxide Species.Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding InteractionsInfluence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome oxidase inspired low-spin heme-peroxo-copper complexesHeme-Cu Binucleating Ligand Supports Heme/O2 and FeII-CuI/O2 Reactivity Providing High- and Low-Spin FeIII-Peroxo-CuII ComplexesLigand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a CuII2(O2•-) Complex Driven by Formation of a CuII2(-OOH) Compound with a Strong O-H BondGeometric and Electronic Structure Contributions to O-O Cleavage and the Resultant Intermediate Generated in Heme-Copper OxidasesHeme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•- Complex H-Atom Abstraction ReactivityImpact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates
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description
researcher
@en
wetenschapper
@nl
name
Andrew W Schaefer
@en
Andrew W Schaefer
@nl
type
label
Andrew W Schaefer
@en
Andrew W Schaefer
@nl
prefLabel
Andrew W Schaefer
@en
Andrew W Schaefer
@nl
P31
P496
0000-0001-6565-920X