about
Biosynthesis and function of polyacetylenes and allied natural productsInspirations, discoveries, and future perspectives in total synthesisYessotoxins, a group of marine polyether toxins: an overviewOrganocatalyzed enantioselective desymmetrization of aziridines and epoxidesStereoselective synthesis of benzannulated spiroketals: influence of the aromatic ring on reactivity and conformation.Water-driven ligations using cyclic amino squarates: a class of useful SN1-like reactions.Evidence that epoxide-opening cascades promoted by water are stepwise and become faster and more selective after the first cyclization.Zirconium(IV)- and hafnium(IV)-catalyzed highly enantioselective epoxidation of homoallylic and bishomoallylic alcohols.Synthesis of the QRSTU domain of maitotoxin and its 85-epi- and 86-epi-diastereoisomersHighly α-selective hydrolysis of α,β-epoxyalcohols using tetrabutylammonium fluoride.Electrophilic and nucleophilic enzymatic cascade reactions in biosynthesis.Synthesis of the C'D'E'F' domain of maitotoxinTotal synthesis of the protein phosphatase 2A inhibitor lactodehydrothyrsiferol.Ni(II) salts and 2-propanol effect catalytic reductive coupling of epoxides and alkynesHydroxyl-substituted ladder polyethers via selective tandem epoxidation/cyclization sequence.Characterization of an epoxide hydrolase from the Florida red tide dinoflagellate, Karenia brevisRhodium-catalyzed endo-selective epoxide-opening cascades: formal synthesis of (-)-brevisin.Zirconium(IV)-Catalyzed Ring Opening of on-DNA Epoxides in Water.Green chemistry for chemical synthesis.Entropic factors provide unusual reactivity and selectivity in epoxide-opening reactions promoted by water.The continuing saga of the marine polyether biotoxinsTandem ruthenium-catalyzed redox isomerization--O-conjugate addition: an atom-economic synthesis of cyclic ethers.Gold(I)-catalyzed cascade cyclization of allenyl epoxides.Cascade approach to stereoselective polycyclic ether formation: epoxides as trapping agents in the transposition of allylic alcohols.The biosynthesis of polyketide-derived polycyclic ethers.Organic synthesis "on water".Epoxide-opening cascades in the synthesis of polycyclic polyether natural products.Synthesis of malhamensilipin A exploiting iterative epoxidation/chlorination: experimental and computational analysis of epoxide-derived chloronium ions.The development of endo-selective epoxide-opening cascades in water.Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascadesBiosynthesis and molecular genetics of polyketides in marine dinoflagellates.Green chemistry oriented organic synthesis in water.Polyketide biosynthesis in dinoflagellates: what makes it different?One-pot non-enzymatic formation of firefly luciferin in a neutral buffer from p-benzoquinone and cysteine.Synthesis at the molecular frontier.Functionalized templates for the convergent assembly of polyethers: synthesis of the HIJK rings of gymnocin A.New synthetic strategies for the stereocontrolled synthesis of substituted "skipped" diepoxides.Absolute configuration of brevisamide and brevisin: confirmation of a universal biosynthetic process for Karenia brevis polyethers.Remarkable facilitation of hetero-cycloisomerizations with water and other polar protic solvents: metal-free synthesis of indolizines.Brevisamide: an unprecedented monocyclic ether alkaloid from the dinoflagellate Karenia brevis that provides a potential model for ladder-frame initiation.
P2860
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P2860
description
2007 nî lūn-bûn
@nan
2007 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
Epoxide-opening cascades promoted by water.
@ast
Epoxide-opening cascades promoted by water.
@en
type
label
Epoxide-opening cascades promoted by water.
@ast
Epoxide-opening cascades promoted by water.
@en
prefLabel
Epoxide-opening cascades promoted by water.
@ast
Epoxide-opening cascades promoted by water.
@en
P2860
P356
P1433
P1476
Epoxide-opening cascades promoted by water.
@en
P2093
Timothy F Jamison
P2860
P304
P356
10.1126/SCIENCE.1146421
P407
P577
2007-08-01T00:00:00Z