Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
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The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisPalladium-catalyzed asymmetric allylic alkylation of 2-acylimidazoles as ester enolate equivalents.Mechanistic origin of the stereodivergence in decarboxylative allylationDecarboxylative benzylations of alkynes and ketonesStereospecific decarboxylative allylation of sulfonesIridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones.A Cooperative N-Heterocyclic Carbene/Palladium Catalysis System.Evolution of a unified, stereodivergent approach to the synthesis of communesin F and perophoramidine.Transition metal-catalyzed decarboxylative allylation and benzylation reactionsDeacylative allylation: allylic alkylation via retro-Claisen activation.The palladium catalyzed asymmetric addition of oxindoles and allenes: an atom-economical versatile method for the construction of chiral indole alkaloidsMetal Catalyzed Allylic Alkylation: Its Development in the Trost LaboratoriesPd and Mo Catalyzed Asymmetric Allylic Alkylation.Intercepted Decarboxylative Allylations of Nitroalkanoates.Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones.Palladium-catalyzed allylic alkylation of carboxylic acid derivatives: N-acyloxazolinones as ester enolate equivalents.Migratory decarboxylative coupling of coumarins: synthetic and mechanistic aspects.An Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesDevelopment of asymmetric deacylative allylation.Raising the pKa limit of "soft" nucleophiles in palladium-catalyzed allylic substitutions: application of diarylmethane pronucleophiles.Palladium-catalyzed allylic substitution with (η6-arene-CH2Z)Cr(CO)(3)-based nucleophiles.Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.Divergent synthesis and identification of the cellular targets of deoxyelephantopins.Outer-sphere direction in iridium C-H borylationAsymmetric Dearomatization/Cyclization Enables Access to Polycyclic Chemotypes.Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism.A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene.High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates.Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolatesThe catalytic enantioselective total synthesis of (+)-liphagal.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Pd-catalyzed enantioselective allyl-allyl cross-coupling.The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation.Enantioselective synthesis of α-quaternary Mannich adducts by palladium-catalyzed allylic alkylation: total synthesis of (+)-sibirinine.Palladium-catalyzed asymmetric construction of vicinal all-carbon quaternary stereocenters and its application to the synthesis of cyclotryptamine alkaloids.Towards the Ideal Synthesis of Homoallylic Ketones.Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation: formal synthesis of aspergillide A.Enantioselective palladium-catalyzed decarboxylative allylation of carbazolones and indolones: formal synthesis of (+)-kopsihainanine A.Direct Access to Highly Functionalized Heterocycles through the Condensation of Cyclic Imines and α-Oxoesters.
P2860
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P2860
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
description
2009 nî lūn-bûn
@nan
2009 թուականի Դեկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2009 թվականի դեկտեմբերին հրատարակված գիտական հոդված
@hy
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
name
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@ast
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@en
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@nl
type
label
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@ast
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@en
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@nl
prefLabel
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@ast
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@en
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@nl
P2860
P356
P1476
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.
@en
P2093
Thomas Schmidt
P2860
P304
18343-18357
P356
10.1021/JA9053948
P407
P50
P577
2009-12-01T00:00:00Z