From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry.
about
Molecular chalcoxides (chalcopolyoxometalates): a family of functional materials with emergent properties.Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SNAr chemistryModular molecules: site-selective metal substitution, photoreduction, and chirality in polyoxometalate hybrids.A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands.Chemical adaptability: the integration of different kinds of matter into giant molecular metal oxides.Label-free colorimetric detection of mercury via Hg(2+) ions-accelerated structural transformation of nanoscale metal-oxo clusters.Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions.High-field 95 Mo and 183 W static and MAS NMR study of polyoxometalates.A unique fluoride nanocontainer: porous molecular capsules can accommodate an unusually high number of "rather labile" fluoride anions.Nona-copper(II)-containing 18-tungsto-8-arsenate(III) exhibits antitumor activity.Capsules with highly active pores and interiors: versatile platforms at the nanoscale.Exploring the Molecular Growth of Two Gigantic Half-Closed Polyoxometalate Clusters {Mo180 } and {Mo130 Ce6 }.Self-Templating and In Situ Assembly of a Cubic Cluster-of-Clusters Architecture Based on a {Mo24 Fe12 } Inorganic Macrocycle.Tunable porosities and shapes of fullerene-like spheres.Stepwise-resolved thermodynamics of hydrophobic self-assembly.Which inorganic structures are the most complex?The chain-like polynuclear coordination compounds (ZnBr2)n(18-crown-6)2 (n = 4, 6, 8, 10) and [Zn5Br9][N(Tf2)].Electronic structure and soft-X-ray-induced photoreduction studies of iron-based magnetic polyoxometalates of type {(M)M5}12Fe(III)30 (M = Mo(VI), W(VI)).Adaptive binding and selection of compressed 1,ω-diammonium-alkanes via molecular encapsulation in water.Electronic Structure Studies on the Whole Keplerate Family: Predicting New Members.Assembly of Tungsten-Oxide-Based Pentagonal Motifs in Solution Leads to Nanoscale {W48}, {W56}, and {W92} Polyoxometalate Clusters.Tunable Keplerate Type-Cluster "Mo132 " Cavity with Dicarboxylate Anions.The chloridomolybdenum(III) cluster in [BMIm]4[AgMo10Cl35] with infinite chains of Ag(+)-linked [Mo10Cl35](5-) wheels.Tracking "apolar" NMe4+ ions within two polyoxothiomolybdates that have the same pores: smaller clathrate and larger highly porous clusters in action.Direct Synthesis of Controlled-Size Nanospheres inside Nanocavities of Self-Organized Photopolymerizing Soft Oxometalates [PW12 O40 ]n (n=1100-7500).Anions coordinating anions: analysis of the interaction between anionic Keplerate nanocapsules and their anionic ligands.Record High-Nuclearity Polyoxoniobates: Discrete Nanoclusters {Nb114 }, {Nb81 }, and {Nb52 }, and Extended Frameworks Based on {Cu3 Nb78 } and {Cu4 Nb78 }.Porphyrin-Sensitized Evolution of Hydrogen using Dawson and Keplerate Polyoxometalate Photocatalysts.Giant Hollow Heterometallic Polyoxoniobates with Sodalite-Type Lanthanide-Tungsten-Oxide Cages: Discrete Nanoclusters and Extended Frameworks.Survival of the Fittest Nanojar: Stepwise Breakdown of Polydisperse Cu27-Cu31 Nanojar Mixtures into Monodisperse Cu27(CO3) and Cu31(SO4) Nanojars.Dawson-Type Polyoxomolybdate Anions (P2 Mo18 O626- ) Captured by Ionic Liquid on Graphene Oxide as High-Capacity Anode Material for Lithium-Ion Batteries.The Uptake and Assembly of Alkanes within a Porous Nanocapsule in Water: New Information about Hydrophobic Confinement.An {Fe60} tetrahedral cage: building nanoscopic molecular assemblies through cyanometallate and alkoxo linkers.Self-Sorting of Heteroanions in the Assembly of Cross-Shaped Polyoxometalate Clusters.Synthesis and characterization of [(HPO3)6Mo21O60(H2O)4](8-): a new redox active heteropoly blue cluster with layered shape containing a phosphite template that self-assembles under controlled microwave irradiation.pH-responsive inorganic-organic hybrid supramolecular hydrogels with jellyfish-like switchable chromic luminescence.A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties.A dielectric anomaly observed for doubly reduced mixed-valence polyoxometalate.Postfunctionalization of polyoxometalates: an efficient strategy to construct organic-inorganic zwitterions.A Polyoxoniobate-Polyoxovanadate Double-Anion Catalyst for Simultaneous Oxidative and Hydrolytic Decontamination of Chemical Warfare Agent Simulants.
P2860
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P2860
From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry.
description
2012 nî lūn-bûn
@nan
2012 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած
@hyw
2012 թվականի սեպտեմբերին հրատարակված գիտական հոդված
@hy
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
name
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@ast
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@en
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@nl
type
label
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@ast
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@en
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@nl
prefLabel
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@ast
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@en
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@nl
P2860
P356
P1476
From linking of metal-oxide bu ...... nd towards adaptive chemistry.
@en
P2093
Pierre Gouzerh
P2860
P304
P356
10.1039/C2CS35169B
P50
P577
2012-09-05T00:00:00Z