Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
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Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylationsNickel-Catalyzed Alkyl-Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent.Free Radical Chemistry Enabled by Visible Light-Induced Electron Transfer.Stereoconvergent Negishi Arylations of Racemic Secondary Alkyl Electrophiles: Differentiating between a CF3 and an Alkyl GroupCatalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines.Methyl fluorosulfonyldifluoroacetate (MFSDA): An Underutilised Reagent for Trifluoromethylation.The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations.Copper-Catalyzed Cyclopropanol Ring Opening Csp(3)-Csp(3) Cross-Couplings with (Fluoro)Alkyl Halides.Radical cascade cyclization of 1,n-enynes and diynes for the synthesis of carbocycles and heterocycles.A Mechanistic Investigation of the Visible-Light Photocatalytic Trifluoromethylation of Heterocycles Using CF3 I in Flow.UV light-mediated difunctionalization of alkenes with CF3SO2Na: synthesis of trifluoromethyl phenanthrene and anthrone derivatives.Selective C-H trifluoromethylation of benzimidazoles through photoredox catalysis.Ligand-Controlled Regioselective Copper-Catalyzed Trifluoromethylation To Generate (Trifluoromethyl)allenes.Phosphine-catalyzed enantioselective [3 + 2] cycloadditions of γ-substituted allenoates with β-perfluoroalkyl enones.An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of 18 F-Labeled α-SCF3 Carbonyl Compounds.Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-Methylation of Diazocarbonyl Compounds.Synthesis of Phthalocyanines with a Pentafluorosulfanyl Substituent at Peripheral Positions.A scalable and operationally simple radical trifluoromethylation.Organocatalyzed Trifluoromethylation of Ketones and Sulfonyl Fluorides by Fluoroform under a Superbase System.Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent.Photochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale.Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysisVisible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterOxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols.Fluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks.A vitamin B12 derivative catalyzed electrochemical trifluoromethylation and perfluoroalkylation of arenes and heteroarenes in organic media.C-H Bond Trifluoromethylation of Arenes Enabled by a Robust, High-Valent Nickel(IV) Complex.Two-step conversion of carboxylic esters into distally fluorinated ketones via ring cleavage of cyclopropanol intermediates: application of sulfinate salts as fluoroalkylating reagents.Anionic Derivatives of Perfluorinated Trimethylgold.In situ generation and reactions of p-(trifluoromethyl)benzyl electrophiles: an efficient access to p-(trifluoromethyl)benzyl compounds.Electrophilic trifluoromethylation of carbonyl compounds and their nitrogen derivatives under copper catalysis.Visible-Light Photocatalytic Decarboxylation of α,β-Unsaturated Carboxylic Acids: Facile Access to Stereoselective Difluoromethylated Styrenes in Batch and Flow.Palladium-Catalyzed Fluoroarylation of gem-Difluoroalkenes.Nonconventional difluoroalkylation of C(sp2)-H bonds through hydroarylation.Direct and Autocatalytic Reductive Elimination from Gold Complexes ([(Ph3 P)Au(Ar)(CF3 )(X)], X=F, Cl, Br, I): The Key Role of Halide Ligands.Copper-catalyzed trifluoromethylazidation and rearrangement of aniline-linked 1,7-enynes: access to CF3-substituted azaspirocyclic dihydroquinolin-2-ones and furoindolines.Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates.Sunlight decatungstate photoinduced trifluoromethylations of (hetero)aromatics and electron-poor olefins.Photoinduced Cobalt(III)-Trifluoromethyl Bond Activation Enables Arene C-H Trifluoromethylation.Monofluoromethyl-Substituted Sulfonium Ylides: Electrophilic Monofluoromethylating Reagents with Broad Substrate Scopes.
P2860
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P2860
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
description
2015 nî lūn-bûn
@nan
2015 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2015 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2015年の論文
@ja
2015年論文
@yue
2015年論文
@zh-hant
2015年論文
@zh-hk
2015年論文
@zh-mo
2015年論文
@zh-tw
2015年论文
@wuu
name
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@ast
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@en
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@nl
type
label
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@ast
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@en
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@nl
prefLabel
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@ast
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@en
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
@nl
P356
P1433
P1476
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes
@en
P2093
Concepción Alonso
Gloria Rubiales
P304
P356
10.1021/CR500368H
P577
2015-01-30T00:00:00Z