Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
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Undirected, Homogeneous C-H Bond Functionalization: Challenges and OpportunitiesRadicals: Reactive Intermediates with Translational PotentialExpeditious diastereoselective synthesis of elaborated ketones via remote Csp(3)-H functionalizationC-H activation generates period-shortening molecules that target cryptochrome in the mammalian circadian clock.Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes.Late Stage Azidation of Complex Molecules.Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.Synthetic approaches towards alkaloids bearing α-tertiary amines.Evolution of C-H Bond Functionalization from Methane to MethodologyMetal-Catalysed Azidation of Organic MoleculesEnantioselective Chemo- and Biocatalysis: Partners in Retrosynthesis.Triiodide-Mediated δ-Amination of Secondary C-H Bonds.Applications of Nonenzymatic Catalysts to the Alteration of Natural Products.A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp(3))-H amination.Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relayA visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C-H bondsIodine(III) Reagents in Radical ChemistryThree-Component Azidation of Styrene-Type Double Bonds: Light-Switchable Behavior of a Copper Photoredox Catalyst.Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins.A unified photoredox-catalysis strategy for C(sp3)-H hydroxylation and amidation using hypervalent iodineRegioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes.Enantioselective, intermolecular benzylic C-H amination catalysed by an engineered iron-haem enzyme.Reactions of hexadehydro-Diels-Alder benzynes with structurally complex multifunctional natural products.Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines.Metal-catalyzed electrochemical diazidation of alkenes.Direct Catalytic Synthesis of Unprotected 2-Amino-1-Phenylethanols from Alkenes by Using Iron(II) Phthalocyanine.Preparation, Structure, and Reactivity of Pseudocyclic Benziodoxole Tosylates: New Hypervalent Iodine Oxidants and Electrophiles.Stereoselective and Enantiospecific Mono- and Bis-C-H Azidation of Tröger Bases: Insight on Bridgehead Iminium Intermediates and Application to Anion-Binding Catalysis.Divergent Access to (1,1) and (1,2)-Azidolactones from Alkenes using Hypervalent Iodine Reagents.Teaching Old Compounds New Tricks: DDQ-Photocatalyzed C-H Amination of Arenes with Carbamates, Urea, and N-Heterocycles.Regio- and Stereoselective Iron-Catalyzed Oxyazidation of Enamides Using a Hypervalent Iodine Reagent.Site-Selective Copper-Catalyzed Amination and Azidation of Arenes and Heteroarenes via Deprotonative Zincation.Oxygenation of Simple Olefins through Selective Allylic C-C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes.Sulfamate Esters Guide Selective Radical-Mediated Chlorination of Aliphatic C-H Bonds.C-H Xanthylation: A Synthetic Platform for Alkane Functionalization.Ritter-type amination of C-H bonds at tertiary carbon centers using iodic acid as an oxidant.Copper-catalyzed intermolecular chloroazidation of α,β-unsaturated amides.Copper-catalyzed radical reactions of 2-azido-N-arylacrylamides with 1-(trifluoromethyl)-1,2-benziodoxole and 1-azidyl-1,2-benziodoxole.Copper-mediated C(sp(3))-H azidation with Me3SiN3: synthesis of imidazoles from ketones and aldehydes.Dual C-H functionalization of N-aryl tetrahydroisoquinolines: a highly diastereoselective synthesis of dibenzo[a,f]quinolizines via visible-light induced oxidation and inverse electron-demand aza-Diels-Alder reaction.
P2860
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P2860
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
description
2015 nî lūn-bûn
@nan
2015 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2015 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2015年の論文
@ja
2015年論文
@yue
2015年論文
@zh-hant
2015年論文
@zh-hk
2015年論文
@zh-mo
2015年論文
@zh-tw
2015年论文
@wuu
name
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
@ast
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
@en
type
label
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
@ast
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
@en
prefLabel
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
@ast
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
@en
P2860
P356
P1433
P1476
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
@en
P2093
Ankit Sharma
P2860
P2888
P304
P356
10.1038/NATURE14127
P407
P577
2015-01-01T00:00:00Z
P5875
P6179
1004636078