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Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related moleculesGroup 14 inorganic hydrocarbon analogues.Cations and dications of heavier group 14 elements in low oxidation states.Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N3)].Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct.Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes.Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions.Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene.Synthesis of a Metallo-Iminosilane via a Silanone-Metal π-Complex.A Disilene Base Adduct with a Dative Si-Si Single Bond.A Persistent 1,2-Dihydrophosphasilene Adduct.Reversible Oxidative Se-Se Coupling of Phosphine Selenides by Ph3 Sb(OTf)2.Calcium Hydride Reactivity: Formation of an Anionic N-Heterocyclic Olefin Ligand.Depolymerization of Poly(phosphinoboranes): From Polymers to Lewis Base Stabilized Monomers.Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.Synthesis, characterization, and electronic structures of a methyl germyliumylidene ion and germylone-group VI metal complexes.Structurally versatile phosphine and amine donors constructed from N-heterocyclic olefin units.Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands.An imine-gallium Lewis pair stabilized oxophosphinidene via an unexpected phosphirene rearrangement.Cationic 5-phosphonio-substituted N-heterocyclic carbenes.Concise access to iminophosphonamide stabilized heteroleptic germylenes: chemical reactivity and structural investigation.Transition metal-mediated donor-acceptor coordination of low-oxidation state Group 14 element halides.Reactivity studies of silylene [PhC(NtBu)2](C5Me5)Si - reactions with [M(COD)Cl]2 (M = Rh(i), Ir(i)), S, Se, Te, and BH3.N-Heterocyclic Carbene Reactivity Towards Mercurous ChlorideInvestigation of N-Heterocyclic Carbene-Supported Group 12 Triflates as Pre-catalysts for Hydrosilylation/Borylation
P2860
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P2860
description
article científic
@ca
article scientifique
@fr
articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
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artigo científico
@pt-br
artikel ilmiah
@id
artikull shkencor
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artículo científico
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name
Donor-acceptor chemistry in the main group.
@en
type
label
Donor-acceptor chemistry in the main group.
@en
prefLabel
Donor-acceptor chemistry in the main group.
@en
P2860
P356
P1433
P1476
Donor-acceptor chemistry in the main group.
@en
P2093
Eric Rivard
P2860
P304
P356
10.1039/C4DT00481G
P407
P577
2014-06-01T00:00:00Z