about
Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-CouplingMass spectrometric monitoring of interfacial photoelectron transfer and imaging of active crystalline facets of semiconductorsRadicals: Reactive Intermediates with Translational PotentialCoordinating activation strategy for C(sp(3))-H/C(sp(3))-H cross-coupling to access β-aromatic α-amino acidsA Molybdenum(0) Isocyanide Analogue of Ru(2,2'-Bipyridine)3 (2+) : A Strong Reductant for Photoredox Catalysis.Radical aryl migration enables diversity-oriented synthesis of structurally diverse medium/macro- or bridged-rings.Metal-Diazo Radicals of α-Carbonyl DiazomethanesCatalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation.Catalysis of Radical Reactions: A Radical Chemistry Perspective.A new era for homolytic aromatic substitution: replacing Bu3SnH with efficient light-induced chain reactions.Cooperative Trifunctional Organocatalysts for Proficient Proton Transfer Reactions.Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization.Functionalization of C-H Bonds by Photoredox Catalysis.Radical cascade cyclization of 1,n-enynes and diynes for the synthesis of carbocycles and heterocycles.Construction of Polycyclic γ-Lactams and Related Heterocycles via Electron Catalysis.Iodine(III) Reagents in Radical ChemistryPalladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen NucleophileThermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts.Mechanistic insights into the potassium tert-butoxide-mediated synthesis of N-heterobiaryls.Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols through Intramolecular Hydroalkoxylation of Allenes.Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates.Intra- versus intermolecular electron transfer in radical nucleophilic aromatic substitution of dihalo(hetero)arenes - a tool for estimating π-conjugation in aromatic systemsGeminal bis-borane formation by borane Lewis acid induced cyclopropyl rearrangement and its frustrated Lewis pair reaction with carbon dioxide.Photoredox catalysis in a complex pharmaceutical setting: toward the preparation of JAK2 inhibitor LY2784544.Characterizing Chain Processes in Visible Light Photoredox Catalysis.A remote C-C bond cleavage-enabled skeletal reorganization: Access to medium-/large-sized cyclic alkenes.Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides.Synthesis of Nitrogen-Containing Rubicene and Tetrabenzopentacene Derivatives.Characterizing metastable states beyond energies and lifetimes: Dyson orbitals and transition dipole moments.A new face of phenalenyl-based radicals in the transition metal-free C-H arylation of heteroarenes at room temperature: trapping the radical initiator via C-C σ-bond formation.Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN.Radical Hydrodehalogenation of Aryl Bromides and Chlorides with Sodium Hydride and 1,4-Dioxane.α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration.Harnessing sunlight without a photosensitizer for highly efficient consecutive [3+2]/[4+2] annulation to synthesize fused benzobicyclic skeletons.Direct arylation of inactivated benzene with aryl acyl peroxides toward biaryls.Communication: Analytic gradients for the complex absorbing potential equation-of-motion coupled-cluster method.Radical-polar crossover reactions of vinylboron ate complexes.Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]n -o-Carboranes (n=1,2) and o-Carborane-Fused Cyclics.Electron-Catalyzed Fluoroalkylation of Vinyl Azides.Radical Arylation of Anilines and Pyrroles via Aryldiazotates.
P2860
Q26747348-CEB4001F-8E65-4372-A3E0-3C2DE7BEE312Q27355419-99E31020-DDA6-42AE-ABA0-CCC7F29C30D1Q28468198-C1B737EB-2CB3-4BB0-B8D3-E96E65C0BED6Q35790900-8FC1C8BC-A40B-4E1F-B6E3-699BD0D10208Q36086801-F76784B1-8B67-4C5F-BE19-3E97ABA1345DQ36231032-7144B582-6F7A-48FD-BCEB-9BDE2459F841Q36670936-1825863D-A100-4814-BD12-5F2ABB59C786Q36774600-707D4905-E2B8-4C43-847D-6BA1A46D07B7Q38605492-EEFA22DA-231C-48E6-9C41-9A57070290DAQ38801502-A0907EB0-BCED-4A3D-86B3-246D64EEDE6DQ38806641-F0533498-F97D-4533-B8C7-99967E54CA81Q38893722-797A9D6C-6022-4C00-ADAA-F0854E8F1C75Q39079192-922D42DD-D2E9-4C9E-ADC0-90A2BDEED6DCQ39354086-E9F24F33-0D35-4302-B2B3-135671058139Q39387066-AC87A29C-EA22-49A3-8793-8D6DC7A0FEB0Q41137826-F222F6EE-8A65-4239-A920-7C82F3A0E774Q41239639-25F0B0F0-9FA4-45E9-B175-D01883A67419Q41640951-E7D39DAB-35AE-4D69-B644-53510723B337Q41819423-E20EA087-6662-489A-9B5B-26ACF0BC056AQ41932779-36274ECA-A528-4379-9047-F103700CD33DQ42157743-6CCD5986-2B32-4EF3-9675-4433F7D538F4Q42258395-DE1A9B7B-4DC6-4D3E-A777-38CA1A52E1CAQ42293588-4D91C8A4-28B9-4748-A883-9EAED6D14CA1Q42545299-DA6E84ED-293F-4B8B-BB7C-1C90FBA9E562Q43133534-ACDC8624-4284-4345-A926-AF83A08720D4Q43624455-BE491CE1-0E40-489D-A854-E702D2E766AFQ45935901-7BA07407-0247-4D27-B763-576608121771Q46004024-EE972F07-0197-4875-A5BA-31835E485300Q46188730-9EF8DF91-F34D-40AB-B868-E52E42C3D90BQ46256471-44EBC9A0-C8B5-4297-8A90-C3160C3152B1Q46753557-97C2CCDF-80C4-4F49-8033-9D6B338B3C95Q47100603-308CD3BA-4042-4091-B8A9-2FA106BE0325Q47106655-5E3AE3AE-F289-4746-8456-51EEF6E2DC4CQ47671813-4CBEFE30-A24D-4292-9CA8-7FD99091F2C6Q47889251-B6456554-75C0-4B09-814C-299014A0AAB9Q48003638-78BCF0AC-2E45-4CC8-8F4A-A093540212ECQ48045939-75D2C154-74FD-4BC4-B795-4E26846E6208Q48141723-46C51570-C8B4-4598-A38D-851B801E7991Q48174654-CA24FD69-E296-4512-9268-DE7F062BB259Q48234906-7580C3C4-4889-4D58-AB12-4B9934AFD96B
P2860
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh
2014年學術文章
@zh-hant
name
The electron is a catalyst.
@en
type
label
The electron is a catalyst.
@en
prefLabel
The electron is a catalyst.
@en
P2860
P356
P1433
P1476
The electron is a catalyst.
@en
P2093
Dennis P Curran
P2860
P2888
P304
P356
10.1038/NCHEM.2031
P577
2014-09-01T00:00:00Z
P6179
1041356851