about
Developing a hetero-alkali-metal chemistry of 2,2,6,6-tetramethylpiperidide (TMP): stoichiometric and structural diversity within a series of lithium/sodium, lithium/potassium and sodium/potassium TMP compoundsStructurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations.Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexationMixed lithium amide-lithium halide compounds: unusual halide-deficient amido metal anionic crowns.Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.Modifying alkylzinc reactivity with 2,2'-dipyridylamide: activation of tBu-Zn bonds for para-alkylation of benzophenone.catena-Poly[sodium-μ2-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-κ(2) N:N'-sodium-bis-[μ2-bis-(trimethyl-sil-yl)aza-nido-κ(2) N:N]]Structurally stimulated deprotonation/alumination of the TMP anion.Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine BoranesStructurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.Experimental and theoretical investigations of the contact ion pairs formed by reactions of the anions [(EPR2)2N]- (R = (i)Pr, (t)Bu; E = S, Se) with the cations [(TePR2)2N]+ (R = (i)Pr, (t)Bu).Synthesis, multinuclear NMR spectra, and X-ray structures of tBu2PNP(I)tBu2 and EPR2NP(I)R2 (E = Se, Te; R = iPr, tBu).Palladium and platinum complexes of tellurium-containing imidodiphosphinate ligands: nucleophilic attack of Li[(P(i)Pr2)(TeP(i)Pr2)N] on coordinated 1,5-cyclooctadiene.Synthetically important alkali-metal utility amides: lithium, sodium, and potassium hexamethyldisilazides, diisopropylamides, and tetramethylpiperidides.Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies.Platinum complexes of naphthalene-1,8-dichalcogen and related polyaromatic hydrocarbon ligands.The preparation and characterisation of bimetallic iridium(II) complexes containing derivatised bridging naphthalene-1,8-disulfur or 4,5-dithiolato acephenanthrylene ligands.A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide.Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates.Experimental and theoretical investigations of the redox behavior of the heterodichalcogenido ligands [(EP(i)Pr2)(TeP(i)Pr2)N](-) (E = S, Se): cyclic cations and acyclic dichalcogenide dimers.Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications.Bis(cyclopentadienyl)titanium complexes of naphthalene-1,8-dithiolates, biphenyl 2,2'-dithiolates, and related ligands.Developing lithium chemistry of 1,2-dihydropyridines: from kinetic intermediates to isolable characterized compounds.Synthesis, NMR characterisation and X-ray structures of mixed chalcogenido PNP ligands containing tellurium: crystal structures of SeiPr2PNP(H)iPr2 and [NaN(EPiPr2)2]infinity (E = Se, Te).Ni[(EPiPr2)2N]2 complexes: stereoisomers (E = Se) and square-planar coordination (E = Te).Platinum complexes of dibenzo[1,2]dithiin, dibenzo[1,2]dithiin oxides and related polyaromatic hydrocarbon ligands.Two alternative approaches to access mixed hydride-amido zinc complexes: synthetic, structural and solution implications.1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications.Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core.Sodium congener of the classical lithium methylchromate dimer: synthetic, X-ray crystallographic, and magnetic studies of Me8Cr2[Na(OEt2)]4.Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole.Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky bis(amido) ligand: deprotomagnesiation reactions of nitrogen-based aromatic substrates.Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-DialkylaluminatesFacile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagentHeterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C–H bond cleavage/dimethylamino capture or intact DMPEA complexLithium, sodium and potassium picolyl complexes: syntheses, structures and bondingAccessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoireAfter-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne productsAmbient temperature zincation of N-Boc pyrrolidine and its solvent dependencyRegioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations
P50
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P50
description
hulumtues
@sq
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
Stuart D Robertson
@ast
Stuart D Robertson
@en
Stuart D Robertson
@es
Stuart D Robertson
@sl
type
label
Stuart D Robertson
@ast
Stuart D Robertson
@en
Stuart D Robertson
@es
Stuart D Robertson
@sl
prefLabel
Stuart D Robertson
@ast
Stuart D Robertson
@en
Stuart D Robertson
@es
Stuart D Robertson
@sl
P106
P21
P31
P496
0000-0002-9330-8770