Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone.
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The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisFormal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation.Transition metal-catalyzed decarboxylative allylation and benzylation reactionsDeacylative allylation: allylic alkylation via retro-Claisen activation.Synthesis and Exploration of Electronically Modified (R)-5,5-Dimethyl-(p-CF3)3-i-PrPHOX in Palladium-Catalyzed Enantio- and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)-(p-CF3)3-t-BuPHOX.Permuting Diels-Alder and Robinson Annulation Stereopatterns.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesAdvances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Enantioselective Access to Robinson Annulation Products and Michael Adducts as Precursors.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.A general enantioselective route to the chamigrene natural product family.Enantioselective total synthesis of the reported structures of (-)-9-epi-presilphiperfolan-1-ol and (-)-presilphiperfolan-1-ol: structural confirmation and reassignment and biosynthetic insights.A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene.The catalytic enantioselective total synthesis of (+)-liphagal.Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes.Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: preparation of mono-, bi-, and tricyclic systems.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation.Enantioselective total synthesis of (+)-cassiol.Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.Enantioselective synthesis of sterically hindered α-allyl-α-aryl oxindoles via palladium-catalysed decarboxylative asymmetric allylic alkylation.A Stereoselective Switch: Enantiodivergent Approach to the Synthesis of Isoflavanones
P2860
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P2860
Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
Catalytic enantioselective app ...... al synthesis of (+)-carissone.
@en
type
label
Catalytic enantioselective app ...... al synthesis of (+)-carissone.
@en
prefLabel
Catalytic enantioselective app ...... al synthesis of (+)-carissone.
@en
P2860
P356
P1433
P1476
Catalytic enantioselective app ...... al synthesis of (+)-carissone.
@en
P2093
Brian M Stoltz
Samantha R Levine
P2860
P304
P356
10.1021/OL802409H
P407
P577
2009-01-01T00:00:00Z