ENDOR/HYSCORE studies of the common intermediate trapped during nitrogenase reduction of N2H2, CH3N2H, and N2H4 support an alternating reaction pathway for N2 reduction
about
Use of electron paramagnetic resonance to solve biochemical problemsMechanism of nitrogen fixation by nitrogenase: the next stageA Sulfide-Bridged Diiron(II) Complex with a cis-N2H4LigandNitrogenase: a draft mechanismInsight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands57Fe ENDOR spectroscopy and 'electron inventory' analysis of the nitrogenase E4 intermediate suggest the metal-ion core of FeMo-cofactor cycles through only one redox coupleUnification of reaction pathway and kinetic scheme for N2 reduction catalyzed by nitrogenaseElectron transfer in nitrogenase catalysis.Conversion of Fe-NH2 to Fe-N2 with release of NH3Nitrogenase reduction of carbon-containing compounds.A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site.Modeling the signatures of hydrides in metalloenzymes: ENDOR analysis of a Di-iron Fe(μ-NH)(μ-H)Fe core.Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.Diiron bridged-thiolate complexes that bind N2 at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox states.Mononuclear five- and six-coordinate iron hydrazido and hydrazine species.Identification of a key catalytic intermediate demonstrates that nitrogenase is activated by the reversible exchange of N₂ for H₂.Nitrite and hydroxylamine as nitrogenase substrates: mechanistic implications for the pathway of N₂ reduction.
P2860
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P2860
ENDOR/HYSCORE studies of the common intermediate trapped during nitrogenase reduction of N2H2, CH3N2H, and N2H4 support an alternating reaction pathway for N2 reduction
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
ENDOR/HYSCORE studies of the c ...... ction pathway for N2 reduction
@en
type
label
ENDOR/HYSCORE studies of the c ...... ction pathway for N2 reduction
@en
prefLabel
ENDOR/HYSCORE studies of the c ...... ction pathway for N2 reduction
@en
P2093
P2860
P356
P1476
ENDOR/HYSCORE studies of the c ...... ction pathway for N2 reduction
@en
P2093
Brett M Barney
Brian M Hoffman
Dennis R Dean
Dmitriy Lukoyanov
Kuppala V Narasimhulu
Rimma I Samoilova
Sergei A Dikanov
Zhi-Yong Yang
P2860
P304
11655-11664
P356
10.1021/JA2036018
P407
P577
2011-07-11T00:00:00Z