ESI-MS, DFT, and synthetic studies on the H(2)-mediated coupling of acetylene: insertion of C=X bonds into rhodacyclopentadienes and Brønsted acid cocatalyzed hydrogenolysis of organorhodium intermediates.
about
Electrospray ionization mass spectrometry: a technique to access the information beyond the molecular weight of the analyteEnantioselective Alcohol C-H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis.Dimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplingsTuning the reactivity of Fe(V)(O) toward C-H bonds at room temperature: effect of waterMechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediateFormation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.Successive C-C coupling of dienes to vicinally dioxygenated hydrocarbons: ruthenium catalyzed [4 + 2] cycloaddition across the diol, hydroxycarbonyl, or dione oxidation levels.Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods.Osmium(0)-Catalyzed C-C Coupling of Ethylene and α-Olefins with Diols, Ketols, or Hydroxy Esters via Transfer Hydrogenation.Redox-triggered C-C coupling of diols and alkynes: synthesis of β,γ-unsaturated α-hydroxyketones and furans by ruthenium-catalyzed hydrohydroxyalkylation.Total synthesis of (+)-trienomycins A and F via C-C bond-forming hydrogenation and transfer hydrogenation.Synthesis of the cytotrienin A core via metal catalyzed C-C coupling.A Metallacycle Fragmentation Strategy for Vinyl Transfer from Enol Carboxylates to Secondary Alcohol C-H Bonds via Osmium- or Ruthenium-Catalyzed Transfer Hydrogenation.Chiral Phosphate in Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition: Ligand, Counterion, or Both?Diols as Dienophiles: Bridged Carbocycles via Ruthenium(0)-Catalyzed Transfer Hydrogenative Cycloadditions of Cyclohexadiene or Norbornadiene.Exploring the effectiveness of different Lewis pair combinations in caged structures for the catalysis of ammonia borane dehydrogenation: a DFT study.Synthesis of the C(1)-C(13) Fragment of Leiodermatolide via Hydrogen-Mediated C-C Bond Formation.
P2860
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P2860
ESI-MS, DFT, and synthetic studies on the H(2)-mediated coupling of acetylene: insertion of C=X bonds into rhodacyclopentadienes and Brønsted acid cocatalyzed hydrogenolysis of organorhodium intermediates.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
ESI-MS, DFT, and synthetic stu ...... f organorhodium intermediates.
@en
ESI-MS, DFT, and synthetic stu ...... f organorhodium intermediates.
@nl
type
label
ESI-MS, DFT, and synthetic stu ...... f organorhodium intermediates.
@en
ESI-MS, DFT, and synthetic stu ...... f organorhodium intermediates.
@nl
prefLabel
ESI-MS, DFT, and synthetic stu ...... f organorhodium intermediates.
@en
ESI-MS, DFT, and synthetic stu ...... f organorhodium intermediates.
@nl
P2093
P2860
P356
P1476
ESI-MS, DFT, and synthetic stu ...... f organorhodium intermediates.
@en
P2093
Byoung Joon Ko
Jennifer S Brodbelt
Jong Rock Kong
Vanessa M Williams
Yogita Mantri
P2860
P304
16054-16062
P356
10.1021/JA906225N
P407
P577
2009-11-01T00:00:00Z