Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran.
about
Structural and Magnetic Diversity in Alkali-Metal Manganate Chemistry: Evaluating Donor and Alkali-Metal Effects in Co-complexation Processes.Developing a hetero-alkali-metal chemistry of 2,2,6,6-tetramethylpiperidide (TMP): stoichiometric and structural diversity within a series of lithium/sodium, lithium/potassium and sodium/potassium TMP compoundsCrystal structure of the inverse crown ether tetra-kis-[μ2-bis-(tri-methyl-sil-yl)amido]-μ4-oxido-dicobalt(II)disodium, [Co2Na2{μ2-N(SiMe3)2}4](μ4-O).Polyimido sulfur anions and ylides.2-Methyltetrahydrofuran (2-MeTHF): a biomass-derived solvent with broad application in organic chemistry.Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.Metal exchange in lithiocuprates: implications for our understanding of structure and reactivity.Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.Beryllium derivatives of a phenyl-substituted β-diketiminate: a well-defined ring opening reaction of tetrahydrofuran.Iron-catalyzed N-alkylation using π-activated ethers as electrophiles.Selective α-metalation of THF by a cationic zirconium complex supported by an (NNNN)-type macrocyclic ligand.Formation of a Ph2PCH(BH3)P(BH3)Ph2 ligand via formal 1,2-borane migration.Formation of unexpected silicon- and disiloxane-bridged multiferrocenyl derivatives bearing Si-O-CH[double bond, length as m-dash]CH2 and Si-(CH2)2C(CH3)3 substituents via cleavage of tetrahydrofuran and trapping of its ring fragments.Optimisation of a lithium magnesiate for use in the non-cryogenic asymmetric deprotonation of prochiral ketones.Robert Mulvey.Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4 [O] Inverse Crown Ether Complex.Mutual Cooperation in the Formal Allyl Alcohol Nucleophilic Substitution and Hydration of Alkynes for the Construction of γ-Substituted Ketones.An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry.Photochemically promoted bond-cleavage and -capture in a diazomethane derivative of a triamidoamine uranium(IV) complex.Magnesiacyclopentadienes as alkaline-earth metallacyclopentadienes: facile synthesis, structural characterization, and synthetic application.Reversible Double CH Bond Activation of Linear and Cyclic Ethers To Form Iridium CarbenesPeroxide solvation by a toroidal lithium inverse crown ether complex assembled by multidentate polyimido sulfonatesHeterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C–H bond cleavage/dimethylamino capture or intact DMPEA complexPre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formationAmbient temperature zincation of N-Boc pyrrolidine and its solvent dependencyMolecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic StudiesMagnesium-Mediated Benzothiazole Activation: A Room-Temperature Cascade of CH Deprotonation, CC Coupling, Ring-Opening, and Nucleophilic Addition ReactionsSynthesis and structure of cationic guanidinate-bridged bimetallic {Li7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions
P2860
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P2860
Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Cleave and capture chemistry i ...... gmentation of tetrahydrofuran.
@en
Cleave and capture chemistry i ...... gmentation of tetrahydrofuran.
@nl
type
label
Cleave and capture chemistry i ...... gmentation of tetrahydrofuran.
@en
Cleave and capture chemistry i ...... gmentation of tetrahydrofuran.
@nl
prefLabel
Cleave and capture chemistry i ...... gmentation of tetrahydrofuran.
@en
Cleave and capture chemistry i ...... gmentation of tetrahydrofuran.
@nl
P2093
P2860
P50
P356
P1433
P1476
Cleave and capture chemistry i ...... gmentation of tetrahydrofuran.
@en
P2093
Alan R Kennedy
Luca Russo
Victoria L Blair
P2860
P2888
P304
P356
10.1038/NCHEM.667
P577
2010-05-23T00:00:00Z
P6179
1004920589