about
The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?Stable cyclic carbenes and related species beyond diaminocarbenes.Bonding and structure of disilenes and related unsaturated group-14 element compounds.Allenes and computational chemistry: from bonding situations to reaction mechanisms.New bonding modes of carbon and heavier group 14 atoms Si-Pb.Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements.Design, Synthesis, and Structural Analysis of Divalent N(I) Compounds and Identification of a New Electron-Donating Ligand.Stable singlet carbenes as mimics for transition metal centers.A Brief Survey of our Contribution to Stable Carbene Chemistry.Diazabutadiene complexes of selenium as Se2+ transfer reagents.The role of 2,6-diaminopyridine ligands in the isolation of an unprecedented, low-valent tin complex.A stable singlet biradicaloid siladicarbene: (L:)2Si.Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands.A mechanistic analysis of the tetrasilyl-substituted trimetallaallenes, >E=E=E< (E = C, Si, Ge, Sn, and Pb).Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*).A coordination compound of Ge(0) stabilized by a diiminopyridine ligand.Carbodicarbenes, carbon(0) derivatives, can dimerize.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Cross-coupling reactions between stable carbenes.Distinguishing carbones from allenes by complexation to AuCl.Bonding in Heavier Group 14 Zero-Valent Complexes-A Combined Maximum Probability Domain and Valence Bond Theory Approach.Highly Bent 1,3-Digerma-2-silaallene.A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity.Extending the chemistry of carbones: P-N bond cleavage via an S(N)2'-like mechanism.A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.Stabilization of heterodiatomic SiC through ligand donation: theoretical investigation of SiC(L)2 (L=NHC(Me) , CAAC(Me) , PMe3 ).Donor-acceptor bonding in novel low-coordinated compounds of boron and group-14 atoms C-Sn.Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2Experimental Charge Density Study of a SilyloneExperimentelle Elektronendichteuntersuchung eines SilylonsEin stabiles biradikaloides Singulett-Siladicarben: (L:)2Si
P2860
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P2860
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh-hant
name
Divalent silicon
@nl
Divalent silicon(0) compounds.
@en
type
label
Divalent silicon
@nl
Divalent silicon(0) compounds.
@en
prefLabel
Divalent silicon
@nl
Divalent silicon(0) compounds.
@en
P2093
P356
P1476
Divalent silicon(0) compounds.
@en
P2093
Gernot Frenking
Nozomi Takagi
Takayasu Shimizu
P304
P356
10.1002/CHEM.200802739
P407
P577
2009-01-01T00:00:00Z