Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis.

Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis.

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http://www.wikidata.org/entity/Q46746934
High Symmetry Dirhodium(II) Paddlewheel Complexes as Chiral CatalystsChiral dirhodium(II) carboxylates and carboxamidates as effective chemzymes in asymmetric synthesis of three-membered carbocycles.A general method for artificial metalloenzyme formation through strain-promoted azide-alkyne cycloaddition.Studies on the stability of cycloprop-2-ene carboxylate dianions and reactions with electrophiles.Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition-Fragmentation Strategy.Directed carbozincation reactions of cyclopropene derivatives.Cyclopropenes in Metallacycle-Mediated Cross-Coupling with Alkynes: Convergent Synthesis of Highly Substituted Vinylcyclopropanes.Helix induction by dirhodium: access to biocompatible metallopeptides with defined secondary structure.Hypervalent iodine(III)-mediated cyclopropa(e)nation of alkenes/alkynes under mild conditions.Direct Synthesis of Chiral Allenoates from the Asymmetric C-H Insertion of α-Diazoesters into Terminal Alkynes.Opening the paddlewheel: unusual coordination of [Mo2] dumbbells in the chain structures of A[Mo2(CF3SO3)5]·2CF3SO3H (A = Na, Rb, Cs).Cyclopropenation of internal alkynylsilanes and diazoacetates catalyzed by copper(i) N-heterocyclic carbene complexes.A new dirhodium catalyst with hemilabile tropolonato ligands for C-H bond functionalization.Brook Rearrangement as a Trigger for the Ring Opening of Strained Carbocycles.Amide-functionalized naphthyridines on a Rh(II) -Rh(II) platform: effect of steric crowding, hemilability, and hydrogen-bonding interactions on the structural diversity and catalytic activity of dirhodium(II) complexes.Microwave-Assisted Synthesis and Characterization of [Rh2(OAc)4(L)2] Paddlewheel Complexes: A Joint Experimental and Computational Study
P2860

Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis.

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http://www.wikidata.org/entity/Q46746934
description
2005 nî lūn-bûn
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2005年の論文
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2005年学术文章
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2005年学术文章
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2005年学术文章
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2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
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2005年學術文章
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2005年學術文章
@zh-hant
name
Catalysis of enantioselective ...... nd complexes of the series Rh2
@nl
Catalysis of enantioselective ...... change and catalyst synthesis.
@en
type
label
Catalysis of enantioselective ...... nd complexes of the series Rh2
@nl
Catalysis of enantioselective ...... change and catalyst synthesis.
@en
prefLabel
Catalysis of enantioselective ...... nd complexes of the series Rh2
@nl
Catalysis of enantioselective ...... change and catalyst synthesis.
@en
P1433
P1476
P2093
P304
P31
P356
P407
P433
P478
P577
P698
P921
P356
P1433
P1476
Catalysis of enantioselective ...... change and catalyst synthesis.
@en
P2093
P304
P31
P356
P407
P433
P478
P577
P698
P921