Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex
about
Synthesis of ammonia directly from air and water at ambient temperature and pressureSynthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia.Alkyne metathesis: development of a novel molybdenum-based catalyst system and its application to the total synthesis of epothilone A and C.Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic.Inner-sphere two-electron reduction leads to cleavage and functionalization of coordinated dinitrogen.Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.Electronic structure and reactivity of three-coordinate iron complexesQuantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes.Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.Recent advances in the development of alkyne metathesis catalysts.Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen.New bonding modes of carbon and heavier group 14 atoms Si-Pb.Catalytic NH3 synthesis using N2/H2 at molecular transition metal complexes - concepts for lead structure determination using computational chemistry.Isolation of a bis(imino)pyridine molybdenum(i) iodide complex through controlled reduction and interconversion of its reaction products.N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions.EPR study of the low-spin [d(3); S =(1)/(2)], Jahn-Teller-active, dinitrogen complex of a molybdenum trisamidoamine.M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).Evaluating molecular cobalt complexes for the conversion of N2 to NH3Preparation of imidazolin-2-iminato molybdenum and tungsten benzylidyne complexes: a new pathway to highly active alkyne metathesis catalysts.Scission of carbon monoxide using TaR3, R=(N(tBu)Ph) or OSi(tBu)3: a DFT investigation.Dissolved N(2) sensing by pH-dependent Ru complexes.Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle by Using a Simple Manganese Complex.Activation of dinitrogen-derived hafnium nitrides for nucleophilic N-C bond formation with a terminal isocyanate.Mononuclear iridium dinitrogen complexes bonded to zeolite HY.Cleavage of Dinitrogen from Forming Gas by a Titanium Molecular System under Ambient Conditions.Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide.NO2 bond cleavage by MoL3 complexes.Dinitrogen and Related Chemistry of the Lanthanides: A Review of the Reductive Capture of Dinitrogen, As Well As Mono- and Di-aza Containing Ligand Chemistry of Relevance to Known and Postulated Metal Mediated Dinitrogen Derivatives.Dinitrogen Splitting Coupled to Protonation.Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.1,8-Bis(silylamido)naphthalene complexes of magnesium and zinc synthesised through alkane elimination reactions.Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework.Nitrogen fixation to cyanide at a molybdenum center.Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes.Cu-mediated nitrogen atom transfer via C≡N bond cleavage.Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine-Titanium Complex.Expanding Boundaries: N2 Cleavage and Functionalization beyond Early Transition Metals.Cleavage and formation of molecular dinitrogen in a single system assisted by molybdenum complexes bearing ferrocenyldiphosphine.Dinitrogen cleavage and hydrogenation by a trinuclear titanium polyhydride complex.The structure and reactivity of iron nitride complexes.
P2860
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P2860
Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex
description
1995 nî lūn-bûn
@nan
1995年の論文
@ja
1995年学术文章
@wuu
1995年学术文章
@zh
1995年学术文章
@zh-cn
1995年学术文章
@zh-hans
1995年学术文章
@zh-my
1995年学术文章
@zh-sg
1995年學術文章
@yue
1995年學術文章
@zh-hant
name
Dinitrogen Cleavage by a Three-Coordinate Molybdenum
@nl
Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex
@en
type
label
Dinitrogen Cleavage by a Three-Coordinate Molybdenum
@nl
Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex
@en
prefLabel
Dinitrogen Cleavage by a Three-Coordinate Molybdenum
@nl
Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex
@en
P1433
P1476
Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex
@en
P2093
Laplaza CE
P304
P356
10.1126/SCIENCE.268.5212.861
P407
P577
1995-05-01T00:00:00Z