On the validity of Wallach's rule: on the density and stability of racemic crystals compared with their chiral counterparts
about
Racemic DNA crystallographyOtto Wallach: founder of terpene chemistry and Nobel Laureate 1910.Spin crossover properties of enantiomers, co-enantiomers, racemates, and co-racemates.Benefits of cocrystallisation in pharmaceutical materials science: an update.Novel tactics for designing water-soluble molecules in drug discovery.Failures of fractional crystallization: ordered co-crystals of isomers and near isomers.Mirror Symmetry Breaking by Chirality Synchronisation in Liquids and Liquid Crystals of Achiral Molecules.(S)-(-)-1-Phenyl-ethanaminium 4-(4,4-di-fluoro-1,3,5,7-tetra-methyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoateQuest for the chemical synthesis of proteins.Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications.From racemic compound to spontaneous resolution: a linker-imposed evolution of chiral [MnMo(9)O(32)](6-)-based polyoxometalate compounds.Discrimination in resolving systems. VI. Comparison of the diastereomers of deoxyephedrinium and ephedrinium 4'-fluoromandelates.Photochromism of polymorphic 4,4'-methylenebis(N-salicylidene-2,6-diisopropylaniline) crystals.Hierarchical self-assembly of enantiopure and racemic helicenes at the liquid/solid interface: from 2D to 3D.Self-assembly of long chain fatty acids: effect of a methyl branch.Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome.Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces.Enantiomeric and diastereoisomeric (mixed) L/ D-octaarginine derivatives - a simple way of modulating the properties of cell-penetrating peptides.Reversible crystal-to-crystal chiral resolution: making/breaking non-bonding SO interactions.One-Dimensionally Disordered Chiral Sorting by Racemic Tiling in a Surface-Confined Supramolecular Assembly of Achiral Tectons.Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying.Possible Case of Halogen Bond-Driven Self-Disproportionation of Enantiomers (SDE) via Achiral Chromatography.Prenucleation Self-Assembly and Chiral Discrimination Mechanisms during Solution Crystallisation of Racemic Diprophylline.Luminescent mechanochromism of a chiral complex: distinct crystal structures and color changes of racemic and homochiral gold(i) isocyanide complexes with a binaphthyl moiety.Is it all in the hinge? A kryptoracemate and three of its alternative racemic polymorphs of an aminonitrile.Crystal structure of a complex between β-glucopyranose and a macrocyclic receptor with dendritic multicharged water solubilizing chains.Disappearing Enantiomorphs: Single Handedness in Racemate Crystals.Assembling Quasi-enantiomeric Octahedral Complexes of Different Metals via Quasi-racemate CrystallizationUltrahigh-resolution centrosymmetric crystal structure of Z-DNA reveals the massive presence of alternate conformations
P2860
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P2860
On the validity of Wallach's rule: on the density and stability of racemic crystals compared with their chiral counterparts
description
im Dezember 1991 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в грудні 1991
@uk
name
On the validity of Wallach's r ...... with their chiral counterparts
@en
On the validity of Wallach's r ...... with their chiral counterparts
@nl
type
label
On the validity of Wallach's r ...... with their chiral counterparts
@en
On the validity of Wallach's r ...... with their chiral counterparts
@nl
prefLabel
On the validity of Wallach's r ...... with their chiral counterparts
@en
On the validity of Wallach's r ...... with their chiral counterparts
@nl
P356
P1476
On the validity of Wallach's r ...... with their chiral counterparts
@en
P2093
Jack D. Dunitz
W. Bernd Schweizer
P304
P356
10.1021/JA00026A015
P407
P577
1991-12-01T00:00:00Z