Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation
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Structural and Magnetic Diversity in Alkali-Metal Manganate Chemistry: Evaluating Donor and Alkali-Metal Effects in Co-complexation Processes.Templated deprotonative metalation of polyaryl systems: Facile access to simple, previously inaccessible multi-iodoarenes.Ligand-Promoted Meta-C-H Arylation of Anilines, Phenols, and HeterocyclesTrans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.Metal exchange in lithiocuprates: implications for our understanding of structure and reactivity.Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand.Pd(II)-catalysed meta-C-H functionalizations of benzoic acid derivatives.Ligand Promoted meta-C-H Chlorination of Anilines and Phenols.Remote site-selective C-H activation directed by a catalytic bifunctional template.Amide-Directed C-H Sodiation by a Sodium Hydride/Iodide Composite.Activation of Remote meta-C-H Bonds in Arenes with Tethered Alcohols: A Salicylonitrile Template.Meta-Selective C-H Arylation of Aromatic Alcohols with a Readily Attachable and Cleavable Molecular Scaffold.Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers.Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines.Heterodinuclear titanium/zinc catalysis: synthesis, characterization and activity for CO2/epoxide copolymerization and cyclic ester polymerization.Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolide ligand.Access to the meta position of arenes through transition metal catalysed C-H bond functionalisation: a focus on metals other than palladium.Pd-Catalyzed regioselective sequential meta-, ortho-C-H functionalization of arenes: a predictable approach to the synthesis of polysubstituted β-arylethylamines.Palladium-Catalyzed Directed para C-H Functionalization of Phenols.Highly regioselective meta arylation of oxalyl amide-protected β-arylethylamine via the Catellani reaction.Ligand-Promoted Meta-C-H Amination and Alkynylation.Simplifying metal-'ate' chemistry: formation and comprehensive characterisation of a homo-metallic amido lithiate complex.Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole.Synthetic, structural and magnetic implications of introducing 2,2'-dipyridylamide to sodium-ferrate complexes.Synthetic and reactivity studies of hetero-tri-anionic sodium zincates.Directing group assisted meta-hydroxylation by C-H activation.Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic MoleculeAssessing the reactivity of sodium alkyl-magnesiates towards quinoxaline: single electron transfer (SET) vs. nucleophilic alkylation processes
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Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation
description
article publié dans la revue scientifique Science
@fr
im November 2014 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published in Science
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wetenschappelijk artikel
@nl
наукова стаття, опублікована в листопаді 2014
@uk
name
Directed ortho-meta'- and meta ...... base approach to deprotonation
@en
Directed ortho-meta'- and meta ...... base approach to deprotonation
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type
label
Directed ortho-meta'- and meta ...... base approach to deprotonation
@en
Directed ortho-meta'- and meta ...... base approach to deprotonation
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prefLabel
Directed ortho-meta'- and meta ...... base approach to deprotonation
@en
Directed ortho-meta'- and meta ...... base approach to deprotonation
@nl
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P50
P356
P1433
P1476
Strong bases. Directed ortho-m ...... base approach to deprotonation
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Alan R Kennedy
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P304
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10.1126/SCIENCE.1259662
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P577
2014-11-01T00:00:00Z