about
Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable MethodRadicals: Reactive Intermediates with Translational PotentialDifluoromethanesulfonyl hypervalent iodonium ylides for electrophilic difluoromethylthiolation reactions under copper catalysisChemo- and site-selective derivatizations of natural products enabling biological studies.Potent fluorinated agelastatin analogues for chronic lymphocytic leukemia: design, synthesis, and pharmacokinetic studiesPreparation and purification of zinc sulfinate reagents for drug discovery.Divergent synthesis of novel 9-deazaxanthine derivatives via late-stage cross-coupling reactions.Profound methyl effects in drug discovery and a call for new C-H methylation reactions.Academia-industry symbiosis in organic chemistry.Palladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles.Identification of Selective ERRγ Inverse Agonists.Catalytic insertion of aldehydes into dihalonitroacetophenones via sequential bond scission-aldol reaction-acyl transfer.Optimized Synthesis of a Pentafluoro-gem-diol and Conversion to a CF2Br-Glucopyranose through Trifluoroacetate-Release and HalogenationDifluoro-and Trifluoromethylation of Electron-Deficient Alkenes in an Electrochemical Microreactor.Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines.Introduction of fluorine and fluorine-containing functional groups.Sulfinate derivatives: dual and versatile partners in organic synthesis.Recent Advances in the C-H-Functionalization of the Distal Positions in Pyridines and Quinolines.A simple litmus test for aldehyde oxidase metabolism of heteroarenes.Pd-catalyzed α-arylation of α,α-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes.C-H methylation of heteroarenes inspired by radical SAM methyl transferase.Modern advances in heterocyclic chemistry in drug discovery.The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations.Recent Advances in the Synthesis of SCF2 H- and SCF2 FG-Containing Molecules.Direct synthesis of fluorinated heteroarylether bioisosteres.Late-stage deoxyfluorination of alcohols with PhenoFluor.Mild silver-mediated geminal difluorination of styrenes using an air- and moisture-stable fluoroiodane reagent.Palladium-catalyzed difluoromethylation of heteroaryl chlorides, bromides and iodides.Radical C-H functionalization of heteroarenes under electrochemical control.Efficient Difluoromethylation of sp(3) Carbon Nucleophiles by Bromodifluoromethylation Reagents with Organic BasesBioconjugation by native chemical tagging of C-H bonds.Meta-selective C-H functionalization using a nitrile-based directing group and cleavable Si-tether.Radical-based regioselective C-H functionalization of electron-deficient heteroarenes: scope, tunability, and predictability.Copper-mediated difluoromethylation of aryl and vinyl iodides.Practical and innate carbon-hydrogen functionalization of heterocycles.Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols.Simple sulfinate synthesis enables C-H trifluoromethylcyclopropanation.Synergistic effect of ketone and hydroperoxide in Brønsted acid catalyzed oxidative coupling reactions.Copper-mediated difluoromethylation of (hetero)aryl iodides and β-styryl halides with tributyl(difluoromethyl)stannane.Fluoride-catalyzed nucleophilic addition of PhSCF2SiMe3 to anhydrides: synthesis of γ-difluoromethylated γ-lactams.
P2860
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P2860
description
2012 nî lūn-bûn
@nan
2012 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2012 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
name
A new reagent for direct difluoromethylation
@ast
A new reagent for direct difluoromethylation
@en
A new reagent for direct difluoromethylation
@nl
type
label
A new reagent for direct difluoromethylation
@ast
A new reagent for direct difluoromethylation
@en
A new reagent for direct difluoromethylation
@nl
prefLabel
A new reagent for direct difluoromethylation
@ast
A new reagent for direct difluoromethylation
@en
A new reagent for direct difluoromethylation
@nl
P2093
P2860
P3181
P356
P1476
A new reagent for direct difluoromethylation
@en
P2093
Darryl D Dixon
Donna G Blackmond
Janice A Dixon
Michael R Collins
Phil S Baran
Rodrigo A Rodriguez
Ryan D Baxter
Yuta Fujiwara
P2860
P304
P3181
P356
10.1021/JA211422G
P407
P577
2012-01-25T00:00:00Z