Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis
about
Mechanistic insight into the CO2 capture by amidophosphoranes: interplay of the ring strain and the trans influence determines the reactivity of the frustrated Lewis pairs.Synthesis of new asymmetric substituted boron amidines - reactions with CO and transfer hydrogenations of phenylacetylene.Artificial hydrogenases.Chloro- and phenoxy-phosphines in frustrated Lewis pair additions to alkynes.An electrochemical study of frustrated Lewis pairs: a metal-free route to hydrogen oxidationSuperelectrophilic intermediates in nitrogen-directed aromatic borylation.Hydrogen atom storage upon Z-class borane ligand functions: an alternative approach to ligand cooperation.Applications and reactivity trends of homoleptic p-block metal amido reagents.Microfluidic studies of carbon dioxide.A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.Active sites on graphene-based materials as metal-free catalysts.Cooperative Catalysis of Combined Systems of Transition-Metal Complexes with Lewis Acids: Theoretical Understanding.Ab initio molecular dynamics study of hydrogen cleavage by a Lewis base [tBu3P] and a Lewis acid [B(C6F5)3] at the mesoscopic level--dynamics in the solute-solvent molecular clusters.A Highly Reactive Geminal P/B Frustrated Lewis Pair: Expanding the Scope to C-X (X=Cl, Br) Bond Activation.Recent Advances in Boron-Substituted 1,3-Dienes Chemistry: Synthesis and Application.Syntheses, Structures, and Complexation Studies of Tris(organostannyl)methane Derivatives.Exploring the fate of the tris(pentafluorophenyl)borane radical anion in weakly coordinating solvents.Chloro({2-[mesityl(quinolin-8-yl-κN)boryl]-3,5-dimethyl-phenyl}methyl-κC)palladium(II) as a catalyst for Heck reactions.Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.Stable singlet carbenes as mimics for transition metal centers.A Brief Survey of our Contribution to Stable Carbene Chemistry.Hydride-containing models for the active site of the nickel-iron hydrogenases.Mild redox complementation enables H2 activation by [FeFe]-hydrogenase models.Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids.Hydrogen activation by biomimetic [NiFe]-hydrogenase model containing protected cyanide cofactors.Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups.Contrasting Frustrated Lewis Pair Reactivity with Selenium- and Boron-Based Lewis Acids.Enantioselective hydrogenation with chiral frustrated Lewis pairs.Planar chiral organoborane Lewis acids derived from naphthylferrocene.Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3).A combined "electrochemical-frustrated lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes.Theoretical study of H(2) splitting and storage by boron-nitrogen-based systems: a bimolecular case and some qualitative aspects.Dispersion-oriented soft interaction in a frustrated Lewis pair and the entropic encouragement effect in its formation.Bulky derivatives of boranes, boronic acids and boronate esters via reaction with diazomethanes.C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions.Phosphinimine-borane combinations in frustrated Lewis pair chemistry.Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.Light-induced rearrangement of thioether-substituted phosphanide ligands: scope and limitations of a remarkable isomerization.Ab initio dynamics trajectory study of the heterolytic cleavage of H2 by a Lewis acid [B(C6F5)3] and a Lewis base [P(tBu)3].Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes.
P2860
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P2860
Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis
description
2009 nî lūn-bûn
@nan
2009 թուականին հրատարակուած գիտական յօդուած
@hyw
2009 թվականին հրատարակված գիտական հոդված
@hy
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
name
Frustrated Lewis pairs: a new ...... on and hydrogenation catalysis
@ast
Frustrated Lewis pairs: a new ...... on and hydrogenation catalysis
@en
type
label
Frustrated Lewis pairs: a new ...... on and hydrogenation catalysis
@ast
Frustrated Lewis pairs: a new ...... on and hydrogenation catalysis
@en
prefLabel
Frustrated Lewis pairs: a new ...... on and hydrogenation catalysis
@ast
Frustrated Lewis pairs: a new ...... on and hydrogenation catalysis
@en
P356
P1433
P1476
Frustrated Lewis pairs: a new ...... on and hydrogenation catalysis
@en
P2093
Douglas W. Stephan
P356
10.1039/B819621D
P407
P577
2009-01-01T00:00:00Z