A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.
about
N-Methyl-Benzothiazolium Salts as Carbon Lewis Acids for Si-H σ-Bond Activation and Catalytic (De)hydrosilylationSolid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2.Transition Metal-Free Cleavage of CO.Direct Mannich-Type Reactions Promoted by Frustrated Lewis Acid/Brønsted Base Catalysts.Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.A Highly Reactive Geminal P/B Frustrated Lewis Pair: Expanding the Scope to C-X (X=Cl, Br) Bond Activation.Electrophilic phosphonium cations catalyze hydroarylation and hydrothiolation of olefins.Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes.Borane catalysed ring opening and closing cascades of furans leading to silicon functionalized synthetic intermediatesExpanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive AminationsAccessing Two-Coordinate ZnII Organocations by NHC Coordination: Synthesis, Structure, and Use as π-Lewis Acids in Alkene, Alkyne, and CO2 Hydrosilylation.Mechanism of the cooperative Si-H bond activation at Ru-S bonds.N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes.Cleavage of Unstrained C-C Bonds in Acenes by Boron and Light: Transformation of Naphthalene to Benzoborepin.Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions.Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid.Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes.Enantioselective Direct Mannich-Type Reactions Catalyzed by Frustrated Lewis Acid/Brønsted Base Complexes.Stoichiometric and Catalytic C-C and C-H Bond Formation with B(C6 F5 )3 via Cationic Intermediates.Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6 F5 )3 Cannot Do!β-Hydroxy-tetrahydroquinolines from Quinolines Using Chloroborane: Synthesis of the Peptidomimetic FISLE-412.B(C6 F5 )3 -Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes.B(C6 F5 )3 -Catalyzed Cascade Reduction of Pyridines.B(C6F5)3-Catalyzed transfer 1,4-hydrostannylation of α,β-unsaturated carbonyls using iPr-tricarbastannatrane.3-tert-Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert-Butylation of Alkenes.By-Product-Free Siloxane-Bond Formation and Programmed One-Pot Oligosiloxane Synthesis.Catalytic Reductive Pinacol-Type Rearrangement of Unactivated 1,2-Diols through a Concerted, Stereoinvertive Mechanism.Cooperative Activation of Isocyanates by Al-N-Based Active Lewis Pairs and the Generation of a C5 Chain by Simultaneous Formation of Two C-C Bonds.Theoretical design and mechanistic study of the metal-free reduction of CO2 to CO.A constellation of deuterium-labeled silanes as a simple mechanistic probe not requiring absolute configuration determination.Selective C-O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers' Borane Generated In Situ.Continuum in the X-Z---Y weak bonds: Z= main group elements.(C6 F5 )3 B Catalyzed Chemoselective and ortho-Selective Substitution of Phenols with α-Aryl α-Diazoesters.Controlled ring-opening polymerization of α-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs.Heterolytic Si-H Bond Cleavage at a Molybdenum-Oxido-Based Lewis Pair.Transfer Hydrosilylation.Extending the Scope of the B(C6 F5 )3 -Catalyzed C=N Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones.Formal SiH4 chemistry using stable and easy-to-handle surrogates.The Propargyl Rearrangement to Functionalised Allyl-Boron and Borocation Compounds.Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: syntheses, β-Si-H agostic interactions, catalytic hydrosilylation, and insight into mechanism.
P2860
Q31138954-C2E10AD2-00F5-49D6-80B6-BDC165417093Q33753805-2984BB73-C8CD-448A-B111-9A6704B3EB68Q38620616-EB99BE42-5856-4592-87D1-A36A77106ACDQ38808446-37217FD3-4090-4A92-9E7A-535999473F83Q38957956-41F1E382-3856-44F3-A78C-16BEE024DD0FQ39152719-DA0E14FB-18BF-48E7-B126-D3BD445038DFQ40827088-9E054506-46DD-48AC-867E-BD1BC21C4D66Q41175405-C129EEB0-15A6-4E66-B550-2F6E90960517Q42063828-097E617D-02BE-468D-BB9A-70C5E085D2C0Q42081651-39A79B75-26B4-4606-828E-6015DFAFF544Q46304668-4714A601-C3DF-4677-8A6E-3A898A0E2FC1Q47101497-20A61360-1A13-4BB7-84B4-6D93ADF18E64Q47136620-12AB252E-E541-47A2-8FBE-1C1B274FFECCQ47276883-69577588-F3C6-437E-B6FD-7394F8954577Q48095610-1DAFC844-9EEF-4DB0-A020-54A58B6BC4E1Q48118151-4E00C322-8D3A-485D-9FCA-8B25594D3733Q48122344-E56A5929-8772-45A8-A48C-55373CEB1691Q48128969-225B1605-CDBE-4B9C-BE06-1CD64F2FE765Q48133288-58A22B76-D147-45FB-A4F5-B8C221060CB5Q48146350-8C633B90-EB31-4D46-BB49-CFE608BCB2A4Q48238490-30372193-76A1-46FF-92C9-6A5D815DAFFBQ48258429-83CDB842-1172-42EB-98A9-D0C2F6F560AAQ48266233-1C98FDA2-2C74-4855-88D0-CE9261FBEAB9Q48279779-01F47A4F-6E24-4BEC-9D84-FEBBCED858DCQ48281193-133A9D15-1727-4A23-8432-E78F8E95EFE5Q48284550-C34EA2A9-7210-435C-9D54-9CD1A0E32809Q48343692-97303336-D24A-4EF5-9E08-2C1877BE1D10Q48359264-6252C536-AEA1-45E8-8B5F-F6AB643C5DBEQ48630581-39D719DF-D36D-4058-9548-AC25A98ADDD8Q48679531-0C335646-CD7B-45C6-B529-7781436B0706Q50124283-FE908F4B-89A5-4AE2-B40A-AF4D3990DE5AQ50211003-1A616299-1CA8-46AB-96C0-E0F84DEA1878Q50216920-75B26CB2-A9C5-4938-9106-36519F86C936Q50653301-87A27BCF-D606-490C-BBCC-A9D4F4BD6BE4Q52361894-C3E5466C-2F4D-4418-967A-EED6EC6D1ED5Q52860202-BE8AF0ED-FC23-4857-8DC4-9224D02C9C54Q52861241-17180A81-B809-4F42-8BFE-BAAFCE956153Q52862167-469A6512-50E9-4083-9A52-E303A086BF13Q52965867-951E2468-D861-4586-B278-810C6B000488Q53339936-129B814D-D159-4206-B6C4-4A10D68416ED
P2860
A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.
description
2015 nî lūn-bûn
@nan
2015年の論文
@ja
2015年学术文章
@wuu
2015年学术文章
@zh-cn
2015年学术文章
@zh-hans
2015年学术文章
@zh-my
2015年学术文章
@zh-sg
2015年學術文章
@yue
2015年學術文章
@zh
2015年學術文章
@zh-hant
name
A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.
@en
type
label
A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.
@en
prefLabel
A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.
@en
P2860
P356
P1476
A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.
@en
P2093
Julia Hermeke
P2860
P304
P356
10.1039/C4CS00451E
P577
2015-04-01T00:00:00Z