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Organoselenium ligands in catalysis.Palladium, iridium and ruthenium complexes with acyclic imino-N-heterocyclic carbenes and their application in aqua-phase Suzuki-Miyaura cross-coupling reaction and transfer hydrogenation.Synthesis and reactivity of {Ru(p-cymene)}2+ derivatives of [Nb6O19]8-: a rational approach towards fluxional organometallic derivatives of polyoxometalates.Library of second-generation cycloruthenated compounds and evaluation of their biological properties as potential anticancer drugs: passing the nanomolar barrier.Untethered 4,1,2-MC2B10 supraicosahedral metallacarboranes, their C,C'-dimethyl 4,1,6-, 4,1,8- and 4,1,12-MC2B10 analogues, and DFT study of the (4,)1,2- to (4,)1,6-isomerisations of C2B11 carboranes and MC2B10 metallacarboranes.Metal-drug synergy: new ruthenium(II) complexes of ketoconazole are highly active against Leishmania major and Trypanosoma cruzi and nontoxic to human or murine normal cellsHeteroleptic arene Ru(II) dipyrrinato complexes: DNA, protein binding and anti-cancer activity against the ACHN cancer cell line.The Development of Phosphine-Free "Tethered" Ruthenium(II) Catalysts for the Asymmetric Reduction of Ketones and Imines.Synthesis, characterisation and biological activities of [(p-cym)RuX(pz4lut)]n+ and [{(p-cym)RuX}2(μ-pz4lut)]n+ (X = Cl, H2O and pz4lut = α,α,α',α'-tetra(pyrazol-1-yl)-2,6-lutidine).Ruthenium-Arene-β-Carboline Complexes as Potent Inhibitors of Cyclin-Dependent Kinase 1: Synthesis, Characterization and Anticancer Mechanism Studies.Identification of the structural determinants for anticancer activity of a ruthenium arene peptide conjugate.Anticancer activity of hydrogen-bond-stabilized half-sandwich Ru(II) complexes with heterocycles.Anticancer activity of tetracationic arene ruthenium metalla-cycles.In vitro anticancer activity and biologically relevant metabolization of organometallic ruthenium complexes with carbohydrate-based ligands.Dichlorido(furfuryl-amine-κN)(η-hexa-methyl-benzene)-ruthenium(II).Self-assembly of arene ruthenium acylpyrazolone fragments to tetranuclear metallacycles. Molecular structures and solid-state (15)N CPMAS NMR correlations.Self-assembled organometallic [12]metallacrown-3 complexes.Water-soluble ruthenium(II) catalysts [RuCl2(eta6-arene)[P(CH2OH)3]] for isomerization of allylic alcohols and alkyne hydration.Comparison of halogen bonding networks with Ru(ii) complexes and analysis of the influence of the XB interactions on their reactivity.Double deboronation and homometalation of 1,1'-bis(ortho-carborane).The half-sandwich 18- and 16-electron arene ruthenium iminophosphonamide complexes.Structural analysis of ruthenium-arene complexes using ion mobility mass spectrometry, collision-induced dissociation, and DFT.Unprecedented flexibility of the 1,1'-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B-H⇀Ru interactions.Icosahedral metallacarborane/carborane species derived from 1,1'-bis(o-carborane).Synthesis, characterisation and theoretical study of ruthenium 4,4'-bi-1,2,3-triazolyl complexes: fundamental switching of the nature of S1 and T1 states from MLCT to MC.Coordination of bis(azol-1-yl)methane-based bisphosphines towards RuII, RhI, PdII and PtII: synthesis, structural and catalytic studies.An Efficient Method for the Synthesis of Boratrane Complexes of Late Transition Metals.Synthesis and photophysics of extended π-conjugated systems of substituted 10-aryl-pyrenoimidazoles.Amine synthesis through mild catalytic hydrosilylation of imines using polymethylhydroxysiloxane and [RuCl2(arene)]2 catalysts.Chemistry by Nanocatalysis: First example of a solid-supported RAPTA complex for organic reactions in aqueous medium.Organometallic chemistry meets crystal engineering to give responsive crystalline materials.New chemistry of 1,2-closo-P2B10H10 and 1,2-closo-As2B10H10; in silico and gas electron diffraction structures, and new metalladiphospha- and metalladiarsaboranes.Enantioselective addition of arylboronic acids to methyl 2-formylbenzoates by using a ruthenium/Me-BIPAM catalyst for synthesis of chiral 3-aryl-isobenzofuranones.Synthesis, characterization and cytotoxicity of arene-ruthenium(ii) complexes with acylpyrazolones functionalized with aromatic groups in the acyl moiety.Cytotoxic hydrogen bridged ruthenium quinaldamide complexes showing induced cancer cell death by apoptosis.A dinuclear [{(p-cym)Ru(II)Cl}2(μ-bpytz˙(-))](+) complex bridged by a radical anion: synthesis, spectroelectrochemical, EPR and theoretical investigation (bpytz = 3,6-bis(3,5-dimethylpyrazolyl)1,2,4,5-tetrazine; p-cym = p-cymene).Alteration of steric hindrance modulates glutathione resistance and cytotoxicity of three structurally related Ru(II)-p-cymene complexes.A straightforward access to ruthenium-coordinated fluorophosphines from phosphorous oxyacidsSynthesis, reactivity and catalytic activity in transfer hydrogenation of ketones of ruthenium(ii) and ruthenium(iv) complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{NP(S)(OR)2}Ph2(R = Et, Ph)Crystal Structure of Cs4[{(C6H6)Ru}2Nb6O19]·8MeOH·2H2O. Structural Overview of Hybrid Organometallic Hexametalates of Niobium and Tantalum: Alkali Metal Coordination Behavior
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P2860
description
article
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artikull shkencor
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artículu científicu
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wetenschappelijk artikel
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գիտական հոդված
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գիտական յօդուած
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ലേഖനം
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name
16. (η6-Hexamethylbenzene)Ruthenium Complexes
@ast
16. (η6-Hexamethylbenzene)Ruthenium Complexes
@en
type
label
16. (η6-Hexamethylbenzene)Ruthenium Complexes
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16. (η6-Hexamethylbenzene)Ruthenium Complexes
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prefLabel
16. (η6-Hexamethylbenzene)Ruthenium Complexes
@ast
16. (η6-Hexamethylbenzene)Ruthenium Complexes
@en
P2093
P1433
P1476
16. (η6-Hexamethylbenzene)Ruthenium Complexes
@en
P2093
A. K. Smith
M. A. Bennett
Steven Ittel
T. W. Matheson
T.-N. Huang
William Nickerson
P356
10.1002/9780470132524.CH16