about
Carbamoyl radical-mediated synthesis and semipinacol rearrangement of β-lactam diols.Carbon-carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketoneDual visible light photoredox and gold-catalyzed arylative ring expansion.Radical cascade reaction of alkynes with N-fluoroarylsulfonimides and alcohols.Towards a general diastereoselective route to oxabicyclo[3.2.1]octanes via a gold-catalysed cascade reactionHighly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.Total synthesis of (+)-sieboldine a: evolution of a pinacol-terminated cyclization strategy.Elucidation of gibberellin biosynthesis in bacteria reveals convergent evolution.New catalytic approaches towards the enantioselective halogenation of alkenes.Radical aryl migration reactions and synthetic applications.Stereoselective Halogenation in Natural Product Synthesis.The Enzymology of Organic Transformations: A Survey of Name Reactions in Biological Systems.Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis.Tandem C-H oxidation/cyclization/rearrangement and its application to asymmetric syntheses of (-)-brussonol and (-)-przewalskine E.Enzyme-catalyzed cationic epoxide rearrangements in quinolone alkaloid biosynthesis.A semipinacol rearrangement directed by an enzymatic system featuring dual-function FAD-dependent monooxygenase.Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.Catalytic asymmetric homologation of α-ketoesters with α-diazoesters: synthesis of succinate derivatives with chiral quaternary centers.Cascade oxidative dearomatization/semipinacol rearrangement: an approach to 2-spirocyclo-3-oxindole derivatives.Catalytic intermolecular carbon electrophile induced semipinacol rearrangement.Ring Expansion and Skeletal Rearrangement of Propargyl Alcohol Substituted Aziridines Induced by Ruthenium Complexes.Electrophilic iodine(I) compounds induced semipinacol rearrangement via C-X bond cleavage.Propargylic cation-induced intermolecular electrophilic addition–semipinacol rearrangement.A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons.Catalytic Enantioselective Aza-pinacol Rearrangement.Direct Access to N-Unprotected α- and/or β-Tetrasubstituted Amino Acid Esters via Direct Catalytic Mannich-Type Reactions Using N-Unprotected Trifluoromethyl Ketimines.α-Quaternary Mannich Bases through Copper-Catalyzed Amination-Induced 1,2-Rearrangement of Allylic Alcohols.Cycloaddition of cyclobutenone and azomethine imine enabled by chiral isothiourea organic catalysts.Total Synthesis of the Hamigerans.A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids.Total Syntheses of the Tetracyclic Cyclopiane Diterpenes Conidiogenone, Conidiogenol, and Conidiogenone B.Catalytic Asymmetric Construction of α-Quaternary Cyclopentanones and Its Application to the Syntheses of (-)-1,14-Herbertenediol and (-)-Aphanorphine.An Indoxyl-Based Strategy for the Synthesis of Indolines and Indolenines.Asymmetric Total Synthesis of (-)-Maoecrystal V.A Concise Synthesis of Presilphiperfolane Core through a Tandem TMTU-Co-Catalyzed Pauson-Khand Reaction and a 6π Electrocyclization Reaction (TMTU=Tetramethyl Thiourea).A synthetic approach for constructing the 3/6/6/5-fused tetracyclic skeleton of tenuipesine A.SN 2 Reactions at Tertiary Carbon Centers in Epoxides.The design of a spiro-pyrrolidine organocatalyst and its application to catalytic asymmetric Michael addition for the construction of all-carbon quaternary centers.Oxidative radical 1,2-alkylarylation of alkenes with α-C(sp(3))-H bonds of acetonitriles involving 1,2-aryl migration.Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols: synthesis of β-aryl-γ-ketophosphonates.
P2860
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P2860
description
2011 nî lūn-bûn
@nan
2011 թուականի Նոյեմբերին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի նոյեմբերին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Semipinacol Rearrangement in Natural Product Synthesis
@ast
Semipinacol Rearrangement in Natural Product Synthesis
@en
type
label
Semipinacol Rearrangement in Natural Product Synthesis
@ast
Semipinacol Rearrangement in Natural Product Synthesis
@en
prefLabel
Semipinacol Rearrangement in Natural Product Synthesis
@ast
Semipinacol Rearrangement in Natural Product Synthesis
@en
P356
P1433
P1476
Semipinacol rearrangement in natural product synthesis
@en
P2093
Yong-Qiang Tu
Zhen-Lei Song
P304
P356
10.1021/CR200055G
P50
P577
2011-08-18T00:00:00Z