Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.
about
Addition of CF3 across unsaturated moieties: a powerful functionalization toolEnantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Radical aryl migration reactions and synthetic applications.Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones.Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration.Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.A novel strategy for the construction of substituted benzoxazoles via a tandem oxidative process.Two-step conversion of carboxylic esters into distally fluorinated ketones via ring cleavage of cyclopropanol intermediates: application of sulfinate salts as fluoroalkylating reagents.Propargylic cation-induced intermolecular electrophilic addition–semipinacol rearrangement.α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration.Selective Oxytrifluoromethylation of Allylamines with CO2.Alkene 1,2-Difunctionalization by Radical Alkenyl Migration.α-Quaternary Mannich Bases through Copper-Catalyzed Amination-Induced 1,2-Rearrangement of Allylic Alcohols.1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration.Silver-promoted (radio)fluorination of unsaturated carbamates via a radical process.Copper-catalyzed trifluoromethylation of trisubstituted allylic and homoallylic alcohols.Iron-catalyzed trifluoromethylation of enamide.Copper-catalyzed arylsulfonylation of N-arylsulfonyl-acrylamides with arylsulfonohydrazides: synthesis of sulfonated oxindoles.Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration.Oxidative radical 1,2-alkylarylation of alkenes with α-C(sp(3))-H bonds of acetonitriles involving 1,2-aryl migration.Metal-free oxidative radical addition of carbonyl compounds to α,α-diaryl allylic alcohols: synthesis of highly functionalized ketones.Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols: synthesis of β-aryl-γ-ketophosphonates.Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration.A Mn(III)/TEMPO-co-mediated tandem azidation-1,2-carbon migration reaction of allylic silyl ethers.Alkene 1,2-Difunctionalization by Radical Alkenyl Migration
P2860
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P2860
Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh-hant
name
Iron-catalyzed trifluoromethyl ...... ,2-migration of an aryl group.
@en
Iron-catalyzed trifluoromethyl ...... ,2-migration of an aryl group.
@nl
type
label
Iron-catalyzed trifluoromethyl ...... ,2-migration of an aryl group.
@en
Iron-catalyzed trifluoromethyl ...... ,2-migration of an aryl group.
@nl
prefLabel
Iron-catalyzed trifluoromethyl ...... ,2-migration of an aryl group.
@en
Iron-catalyzed trifluoromethyl ...... ,2-migration of an aryl group.
@nl
P2860
P356
P1476
Iron-catalyzed trifluoromethyl ...... ,2-migration of an aryl group.
@en
P2093
Ryo Shimizu
Yoshihiko Usui
P2860
P304
P356
10.1039/C3CC43936D
P407
P577
2013-08-01T00:00:00Z