Evidence for the formation of terminal hydrides by protonation of an asymmetric iron hydrogenase active site mimic.
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Synthesis, Characterization, and Reactivity of Functionalized Trinuclear Iron-Sulfur Clusters - A New Class of Bioinspired Hydrogenase ModelsTerminal vs bridging hydrides of diiron dithiolates: protonation of Fe2(dithiolate)(CO)2(PMe3)4.Small molecule mimics of hydrogenases: hydrides and redox.Artificial hydrogenases.Computational investigation of [FeFe]-hydrogenase models: characterization of singly and doubly protonated intermediates and mechanistic insights.Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates.Stereochemistry of electrophilic attack at 34e⁻ dimetallic complexes: the case of diiron dithiolato carbonyls + MeS⁺.Isomerization of the hydride complexes [HFe2(SR)2(PR3)(x)(CO)(6-x)]+ (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenasesSynthetic models for the active site of the [FeFe]-hydrogenase: catalytic proton reduction and the structure of the doubly protonated intermediate.Terminal hydride in [FeFe]-hydrogenase model has lower potential for H2 production than the isomeric bridging hydride.Unsaturated, mixed-valence diiron dithiolate model for the H(ox) state of the [FeFe] hydrogenaseNew nitrosyl derivatives of diiron dithiolates related to the active site of the [FeFe]-hydrogenases.Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates.Proton reduction to hydrogen in biological and chemical systems.Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe3(CO)7(μ-edt)2] and Phosphine Derivatives [Fe3(CO)7-x (PPh3) x (μ-edt)2] (x = 1, 2) and [Fe3(CO)5(κ(2)-diphosphine)(μ-edt)2] as Proton Reduction Catalysts.Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.Models for the hydrogenases put the focus where it should be--hydrogen.Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.Models of the iron-only hydrogenase: a comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(μ-pdt) as proton-reduction catalysts.Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase.[FeFe] hydrogenase: protonation of {2Fe3S} systems and formation of super-reduced hydride states.Hydride-containing models for the active site of the nickel-iron hydrogenases.Hydrogen activation by biomimetic diiron dithiolates.Crystallographic characterization of a fully rotated, basic diiron dithiolate: model for the H(red) state?Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT.Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2'-bipyridyl ligand.Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States.Reactions of [FeFe]-hydrogenase models involving the formation of hydrides related to proton reduction and hydrogen oxidation.Electronic and molecular structure relations in diiron compounds mimicking the [FeFe]-hydrogenase active site studied by X-ray spectroscopy and quantum chemistry.Bio-inspired hydrogenase models: mixed-valence triion complexes as proton reduction catalysts.New Approach to [FeFe]-Hydrogenase Models Using Aromatic Thioketones
P2860
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P2860
Evidence for the formation of terminal hydrides by protonation of an asymmetric iron hydrogenase active site mimic.
description
2007 nî lūn-bûn
@nan
2007 թուականի Մարտին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի մարտին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
Evidence for the formation of ...... hydrogenase active site mimic.
@ast
Evidence for the formation of ...... hydrogenase active site mimic.
@en
type
label
Evidence for the formation of ...... hydrogenase active site mimic.
@ast
Evidence for the formation of ...... hydrogenase active site mimic.
@en
prefLabel
Evidence for the formation of ...... hydrogenase active site mimic.
@ast
Evidence for the formation of ...... hydrogenase active site mimic.
@en
P2093
P356
P1433
P1476
Evidence for the formation of ...... hydrogenase active site mimic.
@en
P2093
François Y Pétillon
Frédéric Gloaguen
Jean Talarmin
Jean-François Capon
Nelly Kervarec
Philippe Schollhammer
Roger Pichon
Salah Ezzaher
P304
P356
10.1021/IC0703124
P407
P577
2007-03-31T00:00:00Z