Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
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Small molecule mimics of hydrogenases: hydrides and redox.Vibrational analysis of the model complex (mu-edt)[Fe(CO)(3)](2) and comparison to iron-only hydrogenase: the activation scale of hydrogenase model systemsIsomerization of the hydride complexes [HFe2(SR)2(PR3)(x)(CO)(6-x)]+ (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenasesDiiron azadithiolates as models for the [FeFe]-hydrogenase active site and paradigm for the role of the second coordination sphereTerminal hydride in [FeFe]-hydrogenase model has lower potential for H2 production than the isomeric bridging hydride.Synthesis of Diiron(I) Dithiolato Carbonyl ComplexesAza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases.Steric effect of the dithiolato linker on the reduction mechanism of [Fe2(CO)6{μ-(XCH2)2CRR'}] hydrogenase models (X = S, Se).
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P2860
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
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name
Desymmetrized Diiron Azadithio ...... ng the Iron-Only Hydrogenases.
@en
Desymmetrized Diiron Azadithio ...... ng the Iron-Only Hydrogenases.
@nl
type
label
Desymmetrized Diiron Azadithio ...... ng the Iron-Only Hydrogenases.
@en
Desymmetrized Diiron Azadithio ...... ng the Iron-Only Hydrogenases.
@nl
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Desymmetrized Diiron Azadithio ...... ng the Iron-Only Hydrogenases.
@en
Desymmetrized Diiron Azadithio ...... ng the Iron-Only Hydrogenases.
@nl
P2093
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Desymmetrized Diiron Azadithio ...... ng the Iron-Only Hydrogenases.
@en
P2093
Guiseppe Zampella
Jane L Stanley
Luca De Gioia
Scott R Wilson
Thomas B Rauchfuss
Zachariah M Heiden
P2860
P304
P356
10.1021/OM7009599
P577
2008-01-01T00:00:00Z