Direct spectroscopic evidence for a high-spin Fe(IV) intermediate in tyrosine hydroxylase.
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Evidence for the slow reaction of hypoxia-inducible factor prolyl hydroxylase 2 with oxygenEvidence for a high-spin Fe(IV) species in the catalytic cycle of a bacterial phenylalanine hydroxylaseRegulation of phenylalanine hydroxylase: conformational changes upon phenylalanine binding detected by hydrogen/deuterium exchange and mass spectrometryPurification and characterization of the epoxidase catalyzing the formation of fosfomycin from Pseudomonas syringaeCatalytic strategies of the non-heme iron dependent oxygenases and their roles in plant biologySpectroscopy and kinetics of wild-type and mutant tyrosine hydroxylase: mechanistic insight into O2 activationMeasurement of intrinsic rate constants in the tyrosine hydroxylase reactionThe crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathwayElucidation of the Fe(IV)=O intermediate in the catalytic cycle of the halogenase SyrB2.Four-electron oxidation of p-hydroxylaminobenzoate to p-nitrobenzoate by a peroxodiferric complex in AurF from Streptomyces thioluteus.Formation of the iron-oxo hydroxylating species in the catalytic cycle of aromatic amino acid hydroxylases.Structure and reaction mechanism in the heme dioxygenases.Mechanisms of tryptophan and tyrosine hydroxylase.Protein dynamics control the progression and efficiency of the catalytic reaction cycle of the Escherichia coli DNA-repair enzyme AlkBPhenylalanine hydroxylase misfolding and pharmacological chaperones.Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners.Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity.Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.In vivo self-hydroxylation of an iron-substituted manganese-dependent extradiol cleaving catechol dioxygenase.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity.Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: proximity and spin-state reactivity rulesA Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexesMechanism of extradiol aromatic ring-cleaving dioxygenases.Electronic Structure of the Ferryl Intermediate in the α-Ketoglutarate Dependent Non-Heme Iron Halogenase SyrB2: Contributions to H Atom Abstraction ReactivityVersatility of biological non-heme Fe(II) centers in oxygen activation reactions.Spectroscopic Evidence for the Two C-H-Cleaving Intermediates of Aspergillus nidulans Isopenicillin N Synthase.Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sitesSubstrate-triggered formation and remarkable stability of the C-H bond-cleaving chloroferryl intermediate in the aliphatic halogenase, SyrB2A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity.Novel Approaches for the Accumulation of Oxygenated Intermediates to Multi-Millimolar Concentrations.Pulsed EPR study of amino acid and tetrahydropterin binding in a tyrosine hydroxylase nitric oxide complex: evidence for substrate rearrangements in the formation of the oxygen-reactive complex.An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base.Phenylalanine hydroxylase: function, structure, and regulation.Electronic structure analysis of the oxygen-activation mechanism by Fe(II)- and α-ketoglutarate (αKG)-dependent dioxygenases.
P2860
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P2860
Direct spectroscopic evidence for a high-spin Fe(IV) intermediate in tyrosine hydroxylase.
description
2007 nî lūn-bûn
@nan
2007 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
Direct spectroscopic evidence ...... diate in tyrosine hydroxylase.
@ast
Direct spectroscopic evidence ...... diate in tyrosine hydroxylase.
@en
type
label
Direct spectroscopic evidence ...... diate in tyrosine hydroxylase.
@ast
Direct spectroscopic evidence ...... diate in tyrosine hydroxylase.
@en
prefLabel
Direct spectroscopic evidence ...... diate in tyrosine hydroxylase.
@ast
Direct spectroscopic evidence ...... diate in tyrosine hydroxylase.
@en
P2093
P2860
P356
P1476
Direct spectroscopic evidence ...... diate in tyrosine hydroxylase.
@en
P2093
Eric W Barr
J Martin Bollinger
Lana Saleh
Patrick A Frantom
Paul F Fitzpatrick
P2860
P304
11334-11335
P356
10.1021/JA074446S
P407
P577
2007-08-23T00:00:00Z