Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.
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Moving protons and electrons in biomimetic systemsReactivity of an Fe(IV)-Oxo Complex with Protons and OxidantsStrong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-Radical-Cation)(Lewis Acid) versus Mn(V)(O) Porphyrinoid ComplexesAbiotic methanogenesis from organosulphur compounds under ambient conditions.Differences and comparisons of the properties and reactivities of iron(III)-hydroperoxo complexes with saturated coordination sphereHigh-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes.Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation.An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base.Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex.Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase.Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates.A Bispidine Iron(IV)-Oxo Complex in the Entatic State.Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O2 at Fe(ii) centers.Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes.On the reaction mechanism of the complete intermolecular O2 transfer between mononuclear nickel and manganese complexes with macrocyclic ligands.Electronic tuning of iron-oxo-mediated C-H activation: effect of electron-donating ligand on selectivity.Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size.Manganese(II) complexes with Bn-tpen as powerful catalysts of cyclohexene oxidation.Tracking the FeIV(O) intermediate and O-O bond formation of a nonheme iron catalyst for water oxidation.Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported RuII complexes: comparison to bimetallic analogs.Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)-oxo Complexes towards C-H and O-H Bond Activation.Oxygen Atom Transfer Using an Iron(IV)-Oxo Embedded in a Tetracyclic N-Heterocyclic Carbene System: How Does the Reactivity Compare to Cytochrome P450 Compound I?Intermetal oxygen atom transfer from an Fe(V)O complex to a Mn(III) complex: an experimental and theoretical approach.From DNA to catalysis: a thymine-acetate ligated non-heme iron(III) catalyst for oxidative activation of aliphatic C-H bonds.Mechanistic elucidation of C-H oxidation by electron rich non-heme iron(IV)-oxo at room temperature.The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites.The role of molecular oxygen in the iron(III)-promoted oxidative dehydrogenation of amines.ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?Does a higher metal oxidation state necessarily imply higher reactivity toward H-atom transfer? A computational study of C-H bond oxidation by high-valent iron-oxo and -nitrido complexes.Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).Nonheme Iron-Oxo-Catalyzed Methane Formation from Methyl Thioethers: Scope, Mechanism, and Relevance for Natural Systems.Why metal–oxos react with dihydroanthracene and cyclohexadiene at comparable rates, despite having different C–H bond strengths. A computational studyHigh-Valent Iron-Oxo and -Nitrido Complexes: Bonding and ReactivityHydrogen atom abstraction reactions independent of C–H bond dissociation energies of organic substrates in water: significance of oxidant–substrate adduct formation
P2860
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P2860
Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh
2013年學術文章
@zh-hant
name
Nonheme Oxoiron(IV) Complexes ...... try, and Oxidative Reactivity.
@ast
Nonheme Oxoiron(IV) Complexes ...... try, and Oxidative Reactivity.
@en
type
label
Nonheme Oxoiron(IV) Complexes ...... try, and Oxidative Reactivity.
@ast
Nonheme Oxoiron(IV) Complexes ...... try, and Oxidative Reactivity.
@en
prefLabel
Nonheme Oxoiron(IV) Complexes ...... try, and Oxidative Reactivity.
@ast
Nonheme Oxoiron(IV) Complexes ...... try, and Oxidative Reactivity.
@en
P2093
P2860
P356
P1433
P1476
Nonheme Oxoiron(IV) Complexes ...... try, and Oxidative Reactivity.
@en
P2093
Arkadius Waleska
Erik R Farquhar
Jonathan R Frisch
Kallol Ray
Lawrence Que
Marion Kerscher
Michael J Collins
Peter Comba
Timothy A Jackson
P2860
P304
P356
10.1039/C2SC21318D
P577
2013-01-01T00:00:00Z