about
The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.Fluorine in medicinal chemistry: a century of progress and a 60-year retrospective of selected highlights.Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparationCopper-catalyzed trifluoromethylation of unactivated olefinsMechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes.Isolation and Reactivity of Trifluoromethyl Iodonium Salts.Trifluoromethyl ethers--synthesis and properties of an unusual substituent.Chemistry of polyvalent iodine.Rapid and efficient trifluoromethylation of aromatic and heteroaromatic compounds using potassium trifluoroacetate enabled by a flow system.Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective.Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions.Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.Introduction of fluorine and fluorine-containing functional groups.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.New avenues for ligand-mediated processes--expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands.Combination of organotrifluoroborates with photoredox catalysis marking a new phase in organic radical chemistry.Synthetic Approaches to Trifluoromethoxy-Substituted Compounds.Direct C-H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis.Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-Methylation of Diazocarbonyl Compounds.A scalable and operationally simple radical trifluoromethylation.Access to a new class of synthetic building blocks via trifluoromethoxylation of pyridines and pyrimidines.Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri-, Di- and Monofluoromethylations of β-Ketoesters.Oxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex.Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates.The dual role of thiourea in the thiotrifluoromethylation of alkenes.Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols.Efficient access to extended Yagupolskii-Umemoto-type reagents: triflic acid catalyzed intramolecular cyclization of ortho-ethynylaryltrifluoromethylsulfanes.Copper(II)-catalyzed trifluoromethylation of N-aryl imines.In situ generation of PhI(+)CF3 and transition-metal-free oxidative sp2 C-H trifluoromethylation.On Pentakis(pentafluoroethyl)stannate, [Sn(C2 F5 )5 ]- , and the Gas-Free Generation of Pentafluoroethyllithium, LiC2 F5.In situ generation and reactions of p-(trifluoromethyl)benzyl electrophiles: an efficient access to p-(trifluoromethyl)benzyl compounds.A novel catalytic process for trifluoromethylation of bromoaromatic compounds.Paradigm shift from alkaline (earth) metals to early transition metals in fluoroorganometal chemistry: perfluoroalkyl titanocene(III) reagents prepared via not titanocene(II) but titanocene(III) species.Direct Dehydroxytrifluoromethoxylation of Alcohols.Photoinduced Cobalt(III)-Trifluoromethyl Bond Activation Enables Arene C-H Trifluoromethylation.
P2860
Q34105033-080E493B-8DEB-4A3A-81FC-691256ECD580Q34161203-F766579B-0FEF-408F-B6F1-53706A26221EQ34172495-70320FD9-6408-4CA8-A458-648EC1C90CE5Q34207164-54BF00FF-D2EA-4D20-8EC7-D9788699D402Q34216544-C93CCB64-2F1C-45AB-AE42-B6C69547E174Q34987089-7DAF8DF0-96DC-4F1A-AA37-C22DE3F91497Q36165294-710D76A9-C758-45B6-AC28-761DA2E084CBQ36886848-C5833D0E-ACA0-4FF5-95AE-E2FB98C06FACQ36941923-D2962BB1-C5E1-4B98-BFA9-4FBEF45A0862Q37305419-DE7684ED-B402-472C-8F87-9F6124A71961Q37318116-1CC4E98D-6E90-43C4-B499-B1E3454506D4Q37418628-02203F4C-E233-4A3F-9806-DDC9A72838DFQ37779490-D910994C-9B98-49FA-8E16-06C1A1841914Q37785764-E33FECA5-73D6-4186-A648-BBC8B4B70E7EQ37832211-7C30CCF7-063C-448A-AC0A-9597A14B8ED0Q38123135-9B947BDB-7297-4E2E-B927-8331CD43D5E6Q38228126-73681A16-4FF8-4006-AA9E-4B32A3C3F866Q38261804-FA04FA98-8C9E-4317-BC04-BA7FBA0AAE31Q38261980-F47B77EF-1F82-43C1-B7F1-C40DC6CD7194Q38543236-AA2C5CD2-E98B-4D54-BE17-10FCB79E2270Q38855622-9BC56763-D50A-4BC5-A784-B1407A8123CCQ38911117-61231D4D-7FC7-4022-8D43-DF1DA5606390Q41587624-C9431BE2-8ABC-4822-B520-60BA1C96AF7FQ41640907-E740C54C-9A13-45EC-B5F9-4A0EB0AA18A1Q41807180-C4BFE196-AF68-4869-89FA-83F0BB061E18Q41884626-FE1497BE-F6B4-4C4F-BCD0-B62CF1E6332CQ41951098-997C8CB0-E8D4-4D3C-83C9-43EE9DAC697DQ41964675-F61B48CB-B02B-405B-8721-74B78CFAD80CQ42157743-5CDE5F77-C183-4F70-82DC-01B835608AFFQ42293575-3526FC28-4CEC-4CD9-ACF1-40BB9D6FA8D5Q42544898-C1F6E018-64B7-45BD-AEF0-89C90380B5E2Q43219010-85976A07-315B-4520-853B-F499ADCF0967Q43677143-F89A7924-C188-404A-AB8B-88B8016DEBAEQ45719714-D521288D-0E44-47E9-9A29-686BA9D92762Q46275337-CCFEEE96-B7F3-4C47-B08B-B2AB1D41AEE2Q46430865-D337AA28-AA80-47F6-A43A-A0C181290E59Q46854076-075DE64F-0181-475A-AA50-04DF2C3F6CB3Q46941982-87DE230F-5317-41D3-A11E-53F47E05AC41Q47361461-AA213B3F-5D45-4416-AAD0-119973DEC8EBQ48046334-DD8F504D-6A4C-4F2E-82C9-E7A37D5A42E6
P2860
description
1996 nî lūn-bûn
@nan
1996 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
1996 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
1996年の論文
@ja
1996年論文
@yue
1996年論文
@zh-hant
1996年論文
@zh-hk
1996年論文
@zh-mo
1996年論文
@zh-tw
1996年论文
@wuu
name
Electrophilic Perfluoroalkylating Agents.
@ast
Electrophilic Perfluoroalkylating Agents.
@en
Electrophilic Perfluoroalkylating Agents.
@nl
type
label
Electrophilic Perfluoroalkylating Agents.
@ast
Electrophilic Perfluoroalkylating Agents.
@en
Electrophilic Perfluoroalkylating Agents.
@nl
prefLabel
Electrophilic Perfluoroalkylating Agents.
@ast
Electrophilic Perfluoroalkylating Agents.
@en
Electrophilic Perfluoroalkylating Agents.
@nl
P356
P1433
P1476
Electrophilic Perfluoroalkylating Agents.
@en
P2093
Teruo Umemoto
P304
P356
10.1021/CR941149U
P577
1996-08-01T00:00:00Z