The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.
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Catalysis for fluorination and trifluoromethylationMetal-free, cooperative asymmetric organophotoredox catalysis with visible light.Copper-catalyzed trifluoromethylation of unactivated olefinsA simple method for asymmetric trifluoromethylation of N-acyl oxazolidinones via Ru-catalyzed radical addition to zirconium enolates.Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroboratesStereoconvergent Negishi Arylations of Racemic Secondary Alkyl Electrophiles: Differentiating between a CF3 and an Alkyl GroupIsolation and Reactivity of Trifluoromethyl Iodonium Salts.Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective.Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions.Enantioselective organocatalytic synthesis of fluorinated molecules.Recent developments on the trifluoromethylation of (hetero)arenes.Combining transition metal catalysis and organocatalysis--an update.Introduction of fluorine and fluorine-containing functional groups.Synergy, compatibility, and innovation: merging Lewis acids with stereoselective enamine catalysis.Hypervalent iodine: a powerful electrophile for asymmetric α-functionalization of carbonyl compounds.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Enantioselective cooperative catalysis.Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters.Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri-, Di- and Monofluoromethylations of β-Ketoesters.Simple catalytic mechanism for the direct coupling of α-carbonyls with functionalized amines: a one-step synthesis of Plavix.Single enantiomer synthesis of α-(trifluoromethyl)-β-lactam.Enantioselective α-alkenylation of aldehydes with boronic acids via the synergistic combination of copper(II) and amine catalysis.Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis.Photochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale.Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols.Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterSynergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development.Synergistic catalysis: cis-cyclopropanation of benzoxazolesEnantioselective α-arylation of aldehydes via the productive merger of iodonium salts and organocatalysis.Asymmetric oxidative dearomatizations promoted by hypervalent iodine(III) reagents: an opportunity for rational catalyst design?Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.Efficient copper-catalyzed direct intramolecular aminotrifluoromethylation of unactivated alkenes with diverse nitrogen-based nucleophiles.Catalytic asymmetric hydrogenation of α-CF3- or β-CF3-substituted acrylic acids using rhodium(I) complexes with a combination of chiral and achiral ligands.Directing-group-assisted copper-catalyzed olefinic trifluoromethylation of electron-deficient alkenes.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Cascade hydroamination/redox reaction for the synthesis of cyclic aminals catalyzed by a combined gold complex and Brønsted acid.Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers.Rapid access to β-trifluoromethyl-substituted ketones: harnessing inductive effects in Wacker-type oxidations of internal alkenes.Copper-catalyzed trifluoromethylation of N,N-dialkylhydrazones.
P2860
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P2860
The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.
description
2010 nî lūn-bûn
@nan
2010 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2010 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
name
The productive merger of iodon ...... luoromethylation of aldehydes.
@ast
The productive merger of iodon ...... luoromethylation of aldehydes.
@en
The productive merger of iodon ...... luoromethylation of aldehydes.
@nl
type
label
The productive merger of iodon ...... luoromethylation of aldehydes.
@ast
The productive merger of iodon ...... luoromethylation of aldehydes.
@en
The productive merger of iodon ...... luoromethylation of aldehydes.
@nl
prefLabel
The productive merger of iodon ...... luoromethylation of aldehydes.
@ast
The productive merger of iodon ...... luoromethylation of aldehydes.
@en
The productive merger of iodon ...... luoromethylation of aldehydes.
@nl
P2860
P356
P1476
The productive merger of iodon ...... luoromethylation of aldehydes.
@en
P2093
Anna E Allen
David W C Macmillan
P2860
P304
P356
10.1021/JA100748Y
P407
P577
2010-04-01T00:00:00Z