Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
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Cobalt(III)-catalyzed synthesis of indazoles and furans by C-H bond functionalization/addition/cyclization cascades.Scope and Mechanistic Study of the Coupling Reaction of α, β-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling PathwaysRhodium catalyzed chelation-assisted C-H bond functionalization reactionsCopper-catalyzed enantioselective intramolecular alkene amination/intermolecular Heck-type coupling cascade.Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes.Mechanistic study of the oxidative coupling of styrene with 2-phenylpyridine derivatives catalyzed by cationic rhodium(III) via C-H activationConvergent Synthesis of Diverse Nitrogen Heterocycles via Rh(III)-Catalyzed C-H Conjugate Addition/Cyclization Reactions.Rhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles.Copper-catalyzed oxidative Heck reactions between alkyltrifluoroborates and vinyl arenes.Recent advances in the ruthenium-catalyzed hydroarylation of alkynes with aromatics: synthesis of trisubstituted alkenes.Complementary regioselectivity in Rh(III)-catalyzed insertions of potassium vinyltrifluoroborate via C-H activation: preparation and use of 4-trifluoroboratotetrahydroisoquinolones.Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reactionCobalt-catalyzed, aminoquinoline-directed coupling of sp(2) C-H bonds with alkenesRh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters.Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity.Synthesis of imidazo and benzimidazo[2,1-a]isoquinolines by rhodium-catalyzed intramolecular double C-H bond activation.Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids.Synthesis of Phenanthridinones from N-methoxybenzamides and aryltriethoxysilanes through Rh(III)-catalyzed C-H and N-H bond activation.Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C-H Bond Activation.Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis.Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes.Pd-catalyzed C3-selective arylation of pyridines with phenyl tosylates.Towards ideal synthesis: alkenylation of aryl C-H bonds by a Fujiwara-Moritani reaction.Mechanochemical Rhodium(III)-Catalyzed C-H Bond Functionalization of Acetanilides under Solventless Conditions in a Ball Mill.Rhodium(III)-catalyzed cyclative capture approach to diverse 1-aminoindoline derivatives at room temperature.Aerobic oxidative coupling between carbon nucleophiles and allylic alcohols: a strategy to construct β-(hetero)aryl ketones and aldehydes through hydrogen migration.Ruthenium(II)-Catalyzed C-H Difluoromethylation of Ketoximes: Tuning the Regioselectivity from the meta to the para Position.Cobalt-catalyzed aryl C-H activation and highly regioselective intermolecular annulation of sulfonamides with allenes.Ruthenium(II)-Catalyzed Traceless C-H Functionalization Using an N-N Bond as an Internal Oxidant.Rh(iii)-catalyzed C-H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant.DFT studies on the directing group dependent arene-alkene cross-couplings: arene activation vs. alkene activation.Rh(III)-catalyzed oxime ether-directed heteroarylation of arene through oxidative C-H/C-H cross-coupling.Rhodium or ruthenium-catalyzed oxidative C-H/C-H cross-coupling: direct access to extended π-conjugated systems.Rh-catalyzed C-C cleavage of benzyl/allylic alcohols to produce benzyl/allylic amines or other alcohols by nucleophilic addition of intermediate rhodacycles to aldehydes and imines.Total Synthesis of Codeine.Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates.Cobalt-catalyzed chelation assisted C-H allylation of aromatic amides with unactivated olefins.Rhodium(iii)-catalyzed ortho-alkenylation using a cyclic N-phosphoryl ketimine as the directing group.Temperature-controlled redox-neutral ruthenium(ii)-catalyzed regioselective allylation of benzamides with allylic acetates.Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis.
P2860
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P2860
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
description
2010 nî lūn-bûn
@nan
2010 թուականի Դեկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2010 թվականի դեկտեմբերին հրատարակված գիտական հոդված
@hy
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
name
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
@ast
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
@en
type
label
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
@ast
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
@en
prefLabel
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
@ast
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
@en
P2093
P2860
P356
P1433
P1476
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.
@en
P2093
Andy S Tsai
Jonathan A Ellman
Mikaël Brasse
Robert G Bergman
P2860
P304
P356
10.1021/OL102890K
P407
P577
2010-12-22T00:00:00Z