Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity.
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Merging rhodium-catalysed C-H activation and hydroamination in a highly selective [4+2] imine/alkyne annulationThe iron-catalyzed construction of 2-aminopyrimidines from alkynenitriles and cyanamidesFacile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines.Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization.Highly diastereoselective synthesis of tetrahydropyridines by a C-H activation-cyclization-reduction cascadeRhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes.Rh(I)-Catalyzed Cycloisomerization of 1,6-EnynesSynthesis of isoquinuclidines from highly substituted dihydropyridines via the Diels-Alder reaction.Transition metal-mediated synthesis of monocyclic aromatic heterocyclesRhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles.Unified synthesis of mono/bis-arylated phenols via RhIII-catalyzed dehydrogenative coupling.Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C-H activation.Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.O-Acyl oximes: versatile building blocks for N-heterocycle formation in recent transition metal catalysis.Rh(III)-catalyzed decarboxylative coupling of acrylic acids with unsaturated oxime esters: carboxylic acids serve as traceless activators.Associative Covalent Relay: An Oxadiazolone Strategy for Rhodium(III)-Catalyzed Synthesis of Primary Pyridinylamines.Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds.Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study.A coupling of benzamides and donor/acceptor diazo compounds to form γ-lactams via Rh(III)-catalyzed C-H activation.Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic Acid.Rhodium(III)-Catalyzed Allylic C(sp(3))-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles.Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones.Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenes.Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters.Synthesis and reactivity of a ruthenocene-type complex bearing an aromatic π-ligand with the heaviest group 14 element.A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes.Synthesis of Chiral Tertiary Boronic Esters by Oxime-Directed Catalytic Asymmetric Hydroboration.Convergent Synthesis of Diverse Tetrahydropyridines via Rh(I)-Catalyzed C-H Functionalization Sequences.Copper-mediated synthesis of N-alkenyl-α,β-unsaturated nitrones and their conversion to tri- and tetrasubstituted pyridines.Indole synthesis by rhodium(III)-catalyzed hydrazine-directed C-H activation: redox-neutral and traceless by N-N bond cleavage.A regioselective synthesis of 1-haloisoquinolines via ruthenium-catalyzed cyclization of O-methylbenzohydroximoyl halides with alkynes.Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids.Copper-catalyzed direct synthesis of iodoenamides from ketoximes.Direct 2-acetoxylation of quinoline N-oxides via copper catalyzed C-H bond activation.Rhodium(III)-catalyzed vinylic sp2 C-H bond functionalization: efficient synthesis of pyrido[1,2-α]benzimidazoles and imidazo[1,2-α]pyridines.[4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the Cp Ligand.Mechanism of the rhodium(iii)-catalyzed alkenylation reaction of N-phenoxyacetamide with styrene or N-tosylhydrazone: a computational study.Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams.Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system.
P2860
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P2860
Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Pyridine synthesis from oximes and alkynes via rhodium
@nl
Pyridine synthesis from oximes ...... ide complementary selectivity.
@en
type
label
Pyridine synthesis from oximes and alkynes via rhodium
@nl
Pyridine synthesis from oximes ...... ide complementary selectivity.
@en
prefLabel
Pyridine synthesis from oximes and alkynes via rhodium
@nl
Pyridine synthesis from oximes ...... ide complementary selectivity.
@en
P2860
P356
P1476
Pyridine synthesis from oximes ...... ide complementary selectivity.
@en
P2093
Todd K Hyster
P2860
P304
11846-11848
P356
10.1039/C1CC15248C
P407
P577
2011-10-10T00:00:00Z