Ligand steric contours to understand the effects of N-heterocyclic carbene ligands on the reversal of regioselectivity in Ni-catalyzed reductive couplings of alkynes and aldehydes.
about
Recent advances in homogeneous nickel catalysisThe discovery of [Ni(NHC)RCN]2 species and their role as cycloaddition catalysts for the formation of pyridines.Regioselective allene hydroarylation via one-pot allene hydrosilylation/Pd-catalyzed cross-coupling.Mechanistic Evaluation of the Ni(IPr)2-Catalyzed Cycloaddition of Alkynes and Nitriles to Afford Pyridines: Evidence for the Formation of a Key η(1)-Ni(IPr)2(RCN) Intermediate.Dimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplingsRegiocontrol in catalytic reductive couplings through alterations of silane rate dependenceMechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive CouplingsRegioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladium.A streamlined strategy for aglycone assembly and glycosylation.Catalytic selective synthesis.Redox-triggered C-C coupling of diols and alkynes: synthesis of β,γ-unsaturated α-hydroxyketones and furans by ruthenium-catalyzed hydrohydroxyalkylation.From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3 + 2] Cycloaddition.Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones.Nickel-Catalyzed Regiodivergent Approach to Macrolide MotifsComputational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C-C Bond Functionalization of Benzocyclobutenones.Exo-selective reductive macrocyclization of ynals.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Highly enantioselective [3+3] cycloaddition of aromatic azomethine imines with cyclopropanes directed by π-π stacking interactions.Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings.Catalytic defluorinative [3 + 2] cycloaddition of trifluoromethylalkenes with alkynes via reduction of nickel(II) fluoride species.Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes.Quantifying and understanding the steric properties of N-heterocyclic carbenes.NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings.
P2860
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P2860
Ligand steric contours to understand the effects of N-heterocyclic carbene ligands on the reversal of regioselectivity in Ni-catalyzed reductive couplings of alkynes and aldehydes.
description
2011 nî lūn-bûn
@nan
2011 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Ligand steric contours to unde ...... ings of alkynes and aldehydes.
@ast
Ligand steric contours to unde ...... ings of alkynes and aldehydes.
@en
type
label
Ligand steric contours to unde ...... ings of alkynes and aldehydes.
@ast
Ligand steric contours to unde ...... ings of alkynes and aldehydes.
@en
prefLabel
Ligand steric contours to unde ...... ings of alkynes and aldehydes.
@ast
Ligand steric contours to unde ...... ings of alkynes and aldehydes.
@en
P2860
P50
P356
P1476
Ligand steric contours to unde ...... ings of alkynes and aldehydes.
@en
P2860
P304
P356
10.1021/JA202007S
P407
P577
2011-04-20T00:00:00Z