Catalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.
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Total Synthesis, Stereochemical Revision, and Biological Reassessment of Mandelalide A: Chemical Mimicry of Intrafamily Relationships.Diastereo- and enantioselective anti-alkoxyallylation employing allylic gem-dicarboxylates as allyl donors via iridium-catalyzed transfer hydrogenation.anti-Diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol or aldehyde oxidation level: allyl carbonates as allylmetal surrogates.Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol or aldehyde oxidation level.Total synthesis of (+)-roxaticin via C-C bond forming transfer hydrogenation: a departure from stoichiometric chiral reagents, auxiliaries, and premetalated nucleophiles in polyketide construction.Enantioselective iridium-catalyzed vinylogous Reformatsky-aldol reaction from the alcohol oxidation level: linear regioselectivity by way of carbon-bound enolatesIridium-catalyzed anti-diastereo- and enantioselective carbonyl (α-trifluoromethyl)allylation from the alcohol or aldehyde oxidation level.Multifunctional organoboron compounds for scalable natural product synthesis.Dimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplingsSYNTHESIS OF (S,S)-DIISOPROPYL TARTRATE (E)-CROTYLBORONATE AND ITS REACTION WITH ALDEHYDES: (2R,3R,4R)-1,2-DIDEOXY-2-ETHENYL-4,5-O-(1-METHYLETHYLIDENE)-XYLITOL.Ligand steric contours to understand the effects of N-heterocyclic carbene ligands on the reversal of regioselectivity in Ni-catalyzed reductive couplings of alkynes and aldehydes.Ni(II) salts and 2-propanol effect catalytic reductive coupling of epoxides and alkynesRegiocontrol in catalytic reductive couplings through alterations of silane rate dependenceMechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediateEthylene in organic synthesis: a new route to anticholenergic pyrrolidinoindolines, and other molecules with all carbon-quaternary centers via asymmetric hydrovinylation.Enthalpy vs Entropy Driven Complexation of Homoallylic Alcohols by Rh(I) Complexes.Mechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive CouplingsSYNTHESIS OF (+)-B-ALLYLDIISOPINOCAMPHEYLBORANE AND ITS REACTION WITH ALDEHYDES.Formation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids.Axial preferences in allylation reactions via the Zimmerman-Traxler transition state.Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.Enantioselective iridium-catalyzed carbonyl allylation from the alcohol oxidation level via transfer hydrogenation: minimizing pre-activation for synthetic efficiencyDirect Sp3α-C-H activation and functionalization of alcohol and ether.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Structurally defined allyl compounds of main group metals: coordination and reactivity.Recent progress towards transition metal-catalyzed synthesis of γ-lactams.C-H bond functionalization through intramolecular hydride transfer.Asymmetric Iridium-Catalyzed C-C Coupling of Chiral Diols via Site-Selective Redox-Triggered Carbonyl AdditionShuttle Catalysis-New Strategies in Organic Synthesis.Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.Transition metal catalysis-a unique road map in the stereoselective synthesis of 1,3-polyols.Enantioselective carbonyl allylation, crotylation, and tert-prenylation of furan methanols and furfurals via iridium-catalyzed transfer hydrogenation.Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods.Catalytic enantioselective Grignard Nozaki-Hiyama methallylation from the alcohol oxidation level: chloride compensates for π-complex instability.1,n-glycols as dialdehyde equivalents in iridium-catalyzed enantioselective carbonyl allylation and iterative two-directional assembly of 1,3-polyols.Enantioselective carbonyl reverse prenylation from the alcohol or aldehyde oxidation level employing 1,1-dimethylallene as the prenyl donorEnantioselective allylation, crotylation, and reverse prenylation of substituted isatins: iridium-catalyzed C-C bond-forming transfer hydrogenation.
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P2860
Catalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.
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article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on January 2009
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Catalytic carbonyl addition th ...... ormed organometallic reagents.
@en
Catalytic carbonyl addition th ...... ormed organometallic reagents.
@nl
type
label
Catalytic carbonyl addition th ...... ormed organometallic reagents.
@en
Catalytic carbonyl addition th ...... ormed organometallic reagents.
@nl
prefLabel
Catalytic carbonyl addition th ...... ormed organometallic reagents.
@en
Catalytic carbonyl addition th ...... ormed organometallic reagents.
@nl
P2093
P2860
P356
P1476
Catalytic carbonyl addition th ...... ormed organometallic reagents.
@en
P2093
John F Bower
Ryan L Patman
P2860
P356
10.1002/ANIE.200802938
P407
P577
2009-01-01T00:00:00Z