Exercising regiocontrol in palladium-catalyzed asymmetric prenylations and geranylation: unifying strategy toward flustramines A and B.
about
The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisA diastereodivergent synthetic strategy for the syntheses of communesin F and perophoramidine.Rapid synthesis of polyprenylated acylphloroglucinol analogs via dearomative conjunctive allylic annulationEvolution of a unified, stereodivergent approach to the synthesis of communesin F and perophoramidine.Deacylative allylation: allylic alkylation via retro-Claisen activation.Ligand-based virtual screening identifies a family of selective cannabinoid receptor 2 agonists.Metal Catalyzed Allylic Alkylation: Its Development in the Trost LaboratoriesPd and Mo Catalyzed Asymmetric Allylic Alkylation.Intercepted Decarboxylative Allylations of Nitroalkanoates.Catalytic enantioselective synthesis of quaternary carbon stereocentresTandem Rh-catalysis: decarboxylative β-keto acid and alkyne cross-coupling.Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylationRaising the pKa limit of "soft" nucleophiles in palladium-catalyzed allylic substitutions: application of diarylmethane pronucleophiles.Catalytic selective synthesis.Direct construction of vicinal all-carbon quaternary stereocenters in natural product synthesis.Recent Advances on the Total Syntheses of Communesin Alkaloids and Perophoramidine.Doubly prenylated tryptamines: cytotoxicity, antimicrobial activity and cyclisation to the marine natural product flustramine A.Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.Synthesis of 2-oxindoles via 'transition-metal-free' intramolecular dehydrogenative coupling (IDC) of sp(2) C-H and sp(3) C-H bonds.Palladium-catalyzed asymmetric construction of vicinal all-carbon quaternary stereocenters and its application to the synthesis of cyclotryptamine alkaloids.Palladium-catalyzed chemoselective allylic substitution, Suzuki-Miyaura cross-coupling, and allene formation of bifunctional 2-B(pin)-substituted allylic acetate derivatives.Palladium-catalyzed synthesis of N-tert-prenylindoles.A catalytic enantioselective approach to tetrol bearing vicinal all-carbon quaternary stereogenic centers.Rhodium-Catalyzed Regioselective Domino Azlactone-Alkyne Coupling/Aza-Cope Rearrangement: Facile Access to 2-Allyl-3-oxazolin-5-ones and Trisubstituted Pyridines.Construction of the Benzomesembrine Skeleton: Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of α-Naphthols and Subsequent Aza-Michael Reaction.Chemo- and Stereoselective Cross Rauhut-Currier-Type Reaction of Tri-substituted Alkenes Containing Trifluoromethyl Groups.Development of catalytic deacylative alkylations (DaA) of 3-acyl-2-oxindoles: total synthesis of meso-chimonanthine and related alkaloids.Development of the Regiodivergent Asymmetric Prenylation of 3-Substituted Oxindoles.Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines.Regio- and Enantioselective Rhodium-Catalyzed Addition of 1,3-Diketones to Allenes: Construction of Asymmetric Tertiary and Quaternary All Carbon Centers.Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3-Fluorinated and All-Carbon Quaternary Oxindoles.Organocatalytic Michael addition of malonates to isatylidene-3-acetaldehydes: application to the total synthesis of (-)-debromoflustramine E.Enantioselective Synthesis of Quaternary Carbon Stereocenters: Addition of 3-Substituted Oxindoles to Vinyl Sulfone Catalyzed by Pentanidiums.Enantioselective construction of vicinal all-carbon quaternary centers via catalytic double asymmetric decarboxylative allylation.Organocatalytic Highly Enantioselective Substitution of 3-(1-Tosylalkyl)indoles with Oxindoles Enables the First Total Synthesis of (+)-Trigolutes B.Palladium(0)-Catalyzed Intermolecular Arylative Dearomatization of β-Naphthols.Simple indole alkaloids and those with a non-rearranged monoterpenoid unit
P2860
Q33763459-EE60EF8D-CF6E-4E58-B1BD-C6DE8C09D9CFQ33799133-40194B41-D7FB-414D-8021-F969FF5D45D2Q34074463-3EE053EC-D318-46AF-8DA3-2DDBCF0EF8FAQ34841311-25A1AB6E-377B-44DE-9B94-A2C3A8DD0502Q35230150-5A37241A-10A3-43B0-8D85-945BAD37D34DQ35501238-53F2874F-3B77-4491-9FC1-EEF030AD4FB5Q35895833-3628A6F3-0C7F-4147-8CE2-8249471D5459Q36039068-FE078324-839A-4730-BFFD-4C17F6CAA418Q36197976-02FD0474-1D89-49A8-A303-2AD1329E6427Q36420603-C825A938-E948-4DFD-A258-7C624214D9C0Q36853956-440F44C1-436B-40E0-B762-220B052F8AF2Q37222823-CC2332E7-FE35-44A5-A63F-5497977F12E7Q37494848-FF07D2BE-CC40-4CE1-AC7D-2413B87DD883Q38046517-864191A9-4F38-4742-88F3-8BFA3CEDD519Q38579612-95013CDB-F841-4DE5-9D68-785138765F7BQ38583678-17A99E5D-3939-448A-B862-3D8C9D98BF5DQ39113781-348D4839-9307-42AF-9E17-97255744C35AQ41918809-097CC44A-4E4E-478C-AA9F-5FFFB2EB0F57Q42367446-63E0372D-2DFD-4D6F-ABC9-2734898974C9Q42910339-06EB2D90-34C6-4E77-9247-47AA256CDCBBQ42974315-47A2A40B-1363-4B00-9EDD-46D9F1E64D4CQ43076625-CEDEC8D9-0D3B-4AC1-9B41-3BA8B7C9FCB0Q48117433-0539CF2B-AD8A-4BE5-99BD-7FB9FB88B585Q48131644-33033400-6F83-4E41-AE52-1673DAF30568Q48136441-8C7FB7DA-7F3E-4C7B-8AF6-F5DB863A124AQ48201658-44A2200C-B19D-43BF-8CE7-2C18D39DB3F1Q48291459-DA21FE16-6437-4260-8B67-5C7B050CE21DQ48292992-E3CEE372-AC79-4CA8-98C8-E803D47B2900Q48358468-D0C0C5AD-9A85-418E-BFAD-8FFDE27AC6F0Q48364143-B73F9260-BF96-4BAA-85A7-C133FEAE9CCAQ50326087-7CF15D5F-CCFD-4506-A46E-8E5E66DFC76BQ50481464-0083038D-79C3-4D02-A8CC-6C26DCAFF04BQ50882173-EC3D0C5F-7617-4A1F-AC0B-82C829E8CE64Q51757336-750B63E6-E5AA-434D-86A9-02E47F56C0EAQ53251662-A6085F99-8A73-478C-8CA3-AF6D518094E9Q54103017-8972204C-01D5-4D31-826A-4ACD3D1AC31CQ58221078-2CD84884-3566-4946-A673-D7DF48844809
P2860
Exercising regiocontrol in palladium-catalyzed asymmetric prenylations and geranylation: unifying strategy toward flustramines A and B.
description
2011 nî lūn-bûn
@nan
2011 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年学术文章
@wuu
2011年学术文章
@zh-cn
2011年学术文章
@zh-hans
2011年学术文章
@zh-my
2011年学术文章
@zh-sg
2011年學術文章
@yue
name
Exercising regiocontrol in pal ...... y toward flustramines A and B.
@ast
Exercising regiocontrol in pal ...... y toward flustramines A and B.
@en
type
label
Exercising regiocontrol in pal ...... y toward flustramines A and B.
@ast
Exercising regiocontrol in pal ...... y toward flustramines A and B.
@en
prefLabel
Exercising regiocontrol in pal ...... y toward flustramines A and B.
@ast
Exercising regiocontrol in pal ...... y toward flustramines A and B.
@en
P2860
P356
P1476
Exercising regiocontrol in pal ...... y toward flustramines A and B.
@en
P2093
Sushant Malhotra
Walter H Chan
P2860
P304
P356
10.1021/JA2020873
P407
P50
P577
2011-04-26T00:00:00Z