Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.
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Enantioselective construction of remote quaternary stereocentresStereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl AcetatesMultifunctional organoboron compounds for scalable natural product synthesis.Ethylene in organic synthesis: a new route to anticholenergic pyrrolidinoindolines, and other molecules with all carbon-quaternary centers via asymmetric hydrovinylation.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsNickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights.Palladium-Catalyzed Asymmetric Allylic Alkylations with Toluene Derivatives as PronucleophilesEnantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary StereocentersEnantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with AllylB(pin).Diastereocontrol in asymmetric allyl-allyl cross-coupling: stereocontrolled reaction of prochiral allylboronates with prochiral allyl chlorides.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions.Catalytic enantioselective allyl-allyl cross-coupling with a borylated allylboronate.Additive-Free Pd-Catalyzed α-Allylation of Imine-Containing Heterocycles.Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity.Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: The role of ligands.Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism.Congested C-C bonds by Pd-catalyzed enantioselective allyl-allyl cross-coupling, a mechanism-guided solution.Palladium-catalyzed synthesis and isolation of functionalized allylboronic acids: selective, direct allylboration of ketones.Ni- and Pd-catalyzed synthesis of substituted and functionalized allylic boronates.Enantioselective carbocycle formation through intramolecular Pd-catalyzed allyl-aryl cross-coupling.Synthesis and application of β-substituted Pauson-Khand adducts: trifluoromethyl as a removable steering group.Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective allylic cross-coupling with alkylboranes.Directed C-C bond cleavage of a cyclopropane intermediate generated from N-tosylhydrazones and stable enaminones: expedient synthesis of functionalized 1,4-ketoaldehydes.Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation.Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation.Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.Asymmetric Synthesis of α,α-Disubstituted Allylic Amines through Palladium-Catalyzed Allylic Substitution.Synthesis of the natural product descurainolide and cyclic peptides from lignin-derived aromatics.Palladium-Catalyzed Asymmetric Allylic Allylation of Racemic Morita-Baylis-Hillman Adducts.Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes.Iridium-catalyzed enantioselective allyl-allylsilane cross-coupling.Iridium-catalyzed allyl-allyl cross-coupling of allylic carbonates with (E)-1,3-diarylpropenes.Palladium(0)-catalyzed cross-coupling of 1,1-diboronates with vinyl bromides and 1,1-dibromoalkenes.Synthetic Approaches to Mono- and Bicyclic Perortho-Esters with a Central 1,2,4-Trioxane Ring as the Privileged Lead Structure in Antimalarial and Antitumor-Active Peroxides and Clarification of the Peroxide Relevance.Copper-free asymmetric allylic alkylation of trisubstituted cyclic allyl bromides using Grignard reagents.
P2860
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P2860
Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Enantioselective construction ...... ed allyl-allyl cross-coupling.
@en
type
label
Enantioselective construction ...... ed allyl-allyl cross-coupling.
@en
prefLabel
Enantioselective construction ...... ed allyl-allyl cross-coupling.
@en
P2093
P2860
P356
P1476
Enantioselective construction ...... ed allyl-allyl cross-coupling.
@en
P2093
James P Morken
Ping Zhang
Robert E Kyne
P2860
P304
P356
10.1021/JA2039248
P407
P577
2011-06-07T00:00:00Z