Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity.
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Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel CellSynthesis and Characterization of New Trinuclear Copper ComplexesImino-oxy acetic acid dealkylation as evidence for an inner-sphere alcohol intermediate in the reaction catalyzed by peptidylglycine alpha-hydroxylating monooxygenase.Fast O2 binding at dicopper complexes containing Schiff-base dinucleating ligands.Enantioselective synthesis of bicyclo[2.2.2]octenones using a copper-mediated oxidative dearomatization/[4 + 2] dimerization cascade.Nitric oxide generation from heme/copper assembly mediated nitrite reductase activityTuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium.Calix[6]tren and copper(II): a third generation of funnel complexes on the way to redox calix-zymes.Generating Cu(II)-oxyl/Cu(III)-oxo species from Cu(I)-alpha-ketocarboxylate complexes and O2: in silico studies on ligand effects and C-H-activation reactivity.Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity.Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex.Geometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex.Copper-peptide complex structure and reactivity when found in conserved His-X(aa)-His sequencesSulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species.The copper centers of tyramine β-monooxygenase and its catalytic-site methionine variants: an X-ray absorption study.Synthesis, structural, and spectroscopic characterization and reactivities of mononuclear cobalt(III)-peroxo complexes.Cupric superoxo-mediated intermolecular C-H activation chemistry.XAS and DFT investigation of mononuclear cobalt(III) peroxo complexes: electronic control of the geometric structure in CoO2 versus NiO2 systemsRapid C-H bond activation by a monocopper(III)-hydroxide complex.A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity.Dioxygen reactivity of new bispidine-copper complexes.Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water.Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates.Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexesGeometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage.Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations.Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes.Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid.Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group.Effects of thioether substituents on the O2 reactivity of beta-diketiminate-Cu(I) complexes: probing the role of the methionine ligand in copper monooxygenasesMononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivityCopper(I)-alpha-ketocarboxylate complexes: characterization and O2 reactions that yield copper-oxygen intermediates capable of hydroxylating arenesPeroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy.Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO).Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex.Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species.L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes.
P2860
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P2860
Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年論文
@yue
2004年論文
@zh-hant
2004年論文
@zh-hk
2004年論文
@zh-mo
2004年論文
@zh-tw
2004年论文
@wuu
2004年论文
@zh
2004年论文
@zh-cn
name
Oxidant types in copper-dioxyg ...... ure and subsequent reactivity.
@ast
Oxidant types in copper-dioxyg ...... ure and subsequent reactivity.
@en
type
label
Oxidant types in copper-dioxyg ...... ure and subsequent reactivity.
@ast
Oxidant types in copper-dioxyg ...... ure and subsequent reactivity.
@en
prefLabel
Oxidant types in copper-dioxyg ...... ure and subsequent reactivity.
@ast
Oxidant types in copper-dioxyg ...... ure and subsequent reactivity.
@en
P1476
Oxidant types in copper-dioxyg ...... ure and subsequent reactivity.
@en
P2093
Kenneth D Karlin
Lanying Q Hatcher
P2888
P304
P356
10.1007/S00775-004-0578-4
P577
2004-08-10T00:00:00Z