Cupric superoxo-mediated intermolecular C-H activation chemistry.
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Mononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligandsElaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generationCopper active sites in biologyEfficient C-H Bond Activations via O2 Cleavage by a Dianionic Cobalt(II) ComplexCharacterization of a paramagnetic mononuclear nonheme iron-superoxo complex.A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity.Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistryDioxygen reactivity of new bispidine-copper complexes.Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates.Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituentKinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes.Mononuclear nickel(II)-superoxo and nickel(III)-peroxo complexes bearing a common macrocyclic TMC ligand.[CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis?Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group.Structure of the Reduced Copper Active Site in Preprocessed Galactose Oxidase: Ligand Tuning for One-Electron O2 Activation in Cofactor Biogenesis.Mechanism of O2 activation and substrate hydroxylation in noncoupled binuclear copper monooxygenases.Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.Quantum mechanical calculations suggest that lytic polysaccharide monooxygenases use a copper-oxyl, oxygen-rebound mechanism.Excitation wavelength dependent O2 release from copper(II)-superoxide compounds: laser flash-photolysis experiments and theoretical studiesCopper is a Cofactor of the Formylglycine-Generating EnzymeActivation of dioxygen by copper metalloproteins and insights from model complexes.Substrate-Induced Carbon Monoxide Reactivity Suggests Multiple Enzyme Conformations at the Catalytic Copper M-Center of Peptidylglycine Monooxygenase.Side-on cupric-superoxo triplet complexes as competent agents for H-abstraction relevant to the active site of PHM.Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity.Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms.Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex.Investigation of the hydroxylation mechanism of noncoupled copper oxygenases by ab initio molecular dynamics simulations.Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp3 C-H Bonds.Oxygen Activation by Cu LPMOs in Recalcitrant Carbohydrate Polysaccharide Conversion to Monomer Sugars.Reactivity of a stable copper-dioxygen complex.A Chromium(III)-Superoxo Complex as a Three-Electron Oxidant with a Large Tunneling Effect in Multi-Electron Oxidation of NADH Analogues.Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2CuII2(O22-) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity.Electron transfer mechanism of catalytic superoxide dismutation via Cu(ii/i) complexes: evidence of cupric-superoxo/-hydroperoxo species.C-H bond activation by metal-superoxo species: what drives high reactivity?Reactions Catalysed by a Binuclear Copper Complex: Aerobic Cross Dehydrogenative Coupling of N-Aryl Tetrahydroisoquinolines.Nucleophilic reactivity of a copper(II)-superoxide complex.Copper Complexes of “Superpodal” Amine Ligands and Reactivity Studies towards Dioxygen
P2860
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P2860
Cupric superoxo-mediated intermolecular C-H activation chemistry.
description
2011 nî lūn-bûn
@nan
2011 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@ast
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@en
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@nl
type
label
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@ast
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@en
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@nl
prefLabel
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@ast
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@en
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@nl
P2093
P2860
P50
P356
P1476
Cupric superoxo-mediated intermolecular C-H activation chemistry.
@en
P2093
Kenneth D Karlin
Maxime A Siegler
Richard A Himes
Ryan L Peterson
Tomoyoshi Suenobu
P2860
P304
P356
10.1021/JA110466Q
P407
P577
2011-01-25T00:00:00Z