Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.
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Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysisOrganocatalytic Reactions Enabled by N-Heterocyclic CarbenesCatalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene CatalysisDiversity-oriented synthesis of drug-like macrocyclic scaffolds using an orthogonal organo- and metal catalysis strategy.Oxyanion steering and CH-π interactions as key elements in an N-heterocyclic carbene-catalyzed [4 + 2] cycloaddition.A Computational Study of the Origin of Stereoinduction in NHC-Catalyzed Annulation Reactions of α,β-Unsaturated Acyl Azoliums.Asymmetric homoenolate additions to acyl phosphonates through rational design of a tailored N-heterocyclic carbene catalyst.Asymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction.Modulating NHC catalysis with fluorine.Rate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes: a remarkable 2-substituent effect.A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A.Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams.Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines.Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.NHC-catalyzed hydroacylation of styrenes.Controlled β-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control.N-Heterocyclic carbene-triggered transition-metal-free synthesis of 2,3-disubstituted benzofuran derivatives.A facile one-pot synthesis of 2,3-diarylated benzo[b]furans via relay NHC and palladium catalysis.N-Heterocyclic carbene-catalyzed [4 + 2] cyclization of α,β-unsaturated carboxylic acids bearing γ-H with isatins: an enantioselective synthesis of spirocyclic oxindole-dihydropyranones.An NHC-catalyzed in situ activation strategy to β-functionalize saturated carboxylic acid: an enantioselective formal [3+2] annulation for spirocyclic oxindolo-γ-butyrolactones.NHC-catalyzed oxidative γ-addition of α,β-unsaturated aldehydes to isatins: a high-efficiency synthesis of spirocyclic oxindole-dihydropyranones.N-heterocyclic carbene catalyzed homoenolate-addition reaction of enals and nitroalkenes: asymmetric synthesis of 5-carbon-synthon δ-nitroesters.Incorporation of redox-inactive cations promotes iron catalyzed aerobic C-H oxidation at mild potentials.NitrostyreneHighly Enantioselective Intermolecular Stetter Reaction of Simple Acrylates: Synthesis of α-Chiral γ-KetoestersMechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent
P2860
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P2860
Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Catalytic asymmetric intermole ...... o the success of the catalyst.
@ast
Catalytic asymmetric intermole ...... o the success of the catalyst.
@en
type
label
Catalytic asymmetric intermole ...... o the success of the catalyst.
@ast
Catalytic asymmetric intermole ...... o the success of the catalyst.
@en
prefLabel
Catalytic asymmetric intermole ...... o the success of the catalyst.
@ast
Catalytic asymmetric intermole ...... o the success of the catalyst.
@en
P2860
P356
P1476
Catalytic asymmetric intermole ...... o the success of the catalyst.
@en
P2093
Daniel A DiRocco
Elizabeth L Noey
P2860
P304
P356
10.1002/ANIE.201107597
P407
P577
2012-01-26T00:00:00Z