Enantioselective total synthesis of (+)-ibophyllidine via an asymmetric phosphine-catalyzed [3 + 2] annulation.
about
The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Hydroxyproline-derived pseudoenantiomeric [2.2.1] bicyclic phosphines: asymmetric synthesis of (+)- and (-)-pyrrolines.Chiral phosphines in nucleophilic organocatalysisAdvances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs.Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric AnnulationsPhosphine catalysis of allenes with electrophiles.Synthesis of Spirocyclic Indolenines.Enantioselective Synthesis of Isoquinolines: Merging Chiral-Phosphine and Gold Catalysis.Stereoselective Syntheses of α,β-Unsaturated γ-Amino Esters Through Phosphine-Catalyzed γ-Umpolung Additions of Sulfonamides to γ-Substituted Allenoates.Catalytic Asymmetric Total Synthesis of (-)-Actinophyllic Acid.Importance of Intermolecular Hydrogen Bonding for the Stereochemical Control of Allene-Enone (3+2) Annulations Catalyzed by a Bifunctional, Amino Acid Derived Phosphine Catalyst.Multicomponent reactions of phosphines, enynedioates and benzylidene malononitriles generated highly substituted cyclopentenes through an unexpected phosphine α-addition-δ-evolvement of an anion pathway.Catalytic Enantioselective Reaction of Allenylnitriles with Imines Using Chiral Bis(imidazoline)s Palladium(II) Pincer Complexes.Total Synthesis of (-)-Vindorosine.Multifunctional chiral phosphine-catalyzed [3+2] annulation of Morita-Baylis-Hillman carbonates with cyclopentenones: asymmetric synthesis of 4-oxo-hexahydropentalenes.Total Synthesis of Strychnine.Asymmetric aza-Morita-Baylis-Hillman reactions of chiral N-phosphonyl imines with acrylates via GAP chemistry/technology.A phosphine-mediated reaction of cyclic 1,2-diones and 3-alkyl allenoates: an efficient protocol for benzannulation applicable to the synthesis of polycyclic aromatic hydrocarbons.Phosphine-catalyzed [3 + 2] and [4 + 2] annulation reactions of ynones with barbiturate-derived alkenes.PPh3-catalyzed ring-expansion reactions of sulfamate-derived cyclic imines with acetylenedicarboxylates.Bridged [2.2.1] bicyclic phosphine oxide facilitates catalytic γ-umpolung addition-Wittig olefination.Catalytic Enantioselective Synthesis of Guvacine Derivatives through [4 + 2] Annulations of Imines with α-MethylallenoatesCarvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene-Imine [3 + 2] Annulation
P2860
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P2860
Enantioselective total synthesis of (+)-ibophyllidine via an asymmetric phosphine-catalyzed [3 + 2] annulation.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Enantioselective total synthes ...... -catalyzed [3 + 2] annulation.
@ast
Enantioselective total synthes ...... -catalyzed [3 + 2] annulation.
@en
type
label
Enantioselective total synthes ...... -catalyzed [3 + 2] annulation.
@ast
Enantioselective total synthes ...... -catalyzed [3 + 2] annulation.
@en
prefLabel
Enantioselective total synthes ...... -catalyzed [3 + 2] annulation.
@ast
Enantioselective total synthes ...... -catalyzed [3 + 2] annulation.
@en
P2860
P356
P1433
P1476
Enantioselective total synthes ...... -catalyzed [3 + 2] annulation.
@en
P2093
Ian P Andrews
Ohyun Kwon
P2860
P304
P356
10.1039/C2SC20468A
P577
2012-01-01T00:00:00Z