Dioxygen activation by copper, heme and non-heme iron enzymes: comparison of electronic structures and reactivities.
about
Coordination of peroxide to the CuM center of peptidylglycine α-hydroxylating monooxygenase (PHM): structural and computational studyStructure and mechanism of a nonhaem-iron SAM-dependent C-methyltransferase and its engineering to a hydratase and an O-methyltransferaseElaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generationCatalytic Mechanisms of Fe(II)- and 2-Oxoglutarate-dependent OxygenasesPerturbing the Copper(III)–Hydroxide Unit through Ligand Structural VariationScalable C-H Oxidation with Copper: Synthesis of PolyoxypregnanesDinuclear complexes of copper and zinc with m-xylene/cyclohexane-linked bis-aspartic acids: synthesis, characterization, dioxygen activation, and catalytic oxidation of nitrobenzene in pure aqueous solution.Generating Cu(II)-oxyl/Cu(III)-oxo species from Cu(I)-alpha-ketocarboxylate complexes and O2: in silico studies on ligand effects and C-H-activation reactivity.A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration.Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species.Enzymatic functionalization of carbon-hydrogen bonds.Cupric superoxo-mediated intermolecular C-H activation chemistry.Resonance Raman characterization of the peroxo and hydroperoxo intermediates in cytochrome P450.Rapid C-H bond activation by a monocopper(III)-hydroxide complex.Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistryTuning the Reactivity of Mononuclear Nonheme Manganese(IV)-Oxo Complexes by Triflic Acid.Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Sulfur oxygenation in biomimetic non-heme iron-thiolate complexes.Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituentCu-ZSM-5: A biomimetic inorganic model for methane oxidation[CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis?Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity.Inner-sphere mechanism for molecular oxygen reduction catalyzed by copper amine oxidases.Copper(I)-alpha-ketocarboxylate complexes: characterization and O2 reactions that yield copper-oxygen intermediates capable of hydroxylating arenesCopper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO).Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.Fe L- and K-edge XAS of low-spin ferric corrole: bonding and reactivity relative to low-spin ferric porphyrinA [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanolExcitation wavelength dependent O2 release from copper(II)-superoxide compounds: laser flash-photolysis experiments and theoretical studiesCatalytic oxygen activation versus autoxidation for industrial applications: a physicochemical approach.A DFT study of the cis-dihydroxylation of nitroaromatic compounds catalyzed by nitrobenzene dioxygenase.Reactivity of the copper(iii)-hydroxide unit with phenols.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Design and engineering of artificial oxygen-activating metalloenzymes.Copper/alpha-ketocarboxylate chemistry with supporting peralkylated diamines: reactivity of copper(I) complexes and dicopper-oxygen intermediates.Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer.Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido ComplexHydrogen atom abstraction from hydrocarbons by a copper(III)-hydroxide complexMechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex.Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species.
P2860
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P2860
Dioxygen activation by copper, heme and non-heme iron enzymes: comparison of electronic structures and reactivities.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年論文
@yue
2005年論文
@zh-hant
2005年論文
@zh-hk
2005年論文
@zh-mo
2005年論文
@zh-tw
2005年论文
@wuu
2005年论文
@zh
2005年论文
@zh-cn
name
Dioxygen activation by copper, ...... c structures and reactivities.
@ast
Dioxygen activation by copper, ...... c structures and reactivities.
@en
type
label
Dioxygen activation by copper, ...... c structures and reactivities.
@ast
Dioxygen activation by copper, ...... c structures and reactivities.
@en
prefLabel
Dioxygen activation by copper, ...... c structures and reactivities.
@ast
Dioxygen activation by copper, ...... c structures and reactivities.
@en
P1476
Dioxygen activation by copper, ...... c structures and reactivities.
@en
P2093
Andrea Decker
P304
P356
10.1016/J.CBPA.2005.02.012
P577
2005-04-01T00:00:00Z