A bulky biaryl phosphine ligand allows for palladium-catalyzed amidation of five-membered heterocycles as electrophiles
about
Mild Pd-catalyzed aminocarbonylation of (hetero)aryl bromides with a palladacycle precatalystHighly selective palladium-catalyzed cross-coupling of secondary alkylzinc reagents with heteroaryl halides.Mild and general palladium-catalyzed synthesis of methyl aryl ethers enabled by the use of a palladacycle precatalystStructure and Reactivity of [(L•Pd)n•(1,5-cyclooctadiene)] (n=1-2) Complexes Bearing Biaryl Phosphine LigandsSilyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling.Regiospecific N-heteroarylation of amidines for full-color-tunable boron difluoride dyes with mechanochromic luminescence.Rational ligand design for the arylation of hindered primary amines guided by reaction progress kinetic analysis.Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes.In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides.Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts.Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands.Mild and highly selective palladium-catalyzed monoarylation of ammonia enabled by the use of bulky biarylphosphine ligands and palladacycle precatalysts.Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation.An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates.Palladium-catalyzed amination of unprotected five-membered heterocyclic bromidesApplications of Palladium-Catalyzed C-N Cross-Coupling Reactions.The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination.Cu-catalysed oxidative C-H/C-H coupling polymerisation of benzodiimidazoles: an efficient approach to regioregular polybenzodiimidazoles for blue-emitting materials.Rhodium or ruthenium-catalyzed oxidative C-H/C-H cross-coupling: direct access to extended π-conjugated systems.Palladium-Catalyzed C-O Cross-Coupling of Primary Alcohols.Cu-catalyzed amidation of halogenated imidazoles.Base-catalyzed synthesis of aryl amides from aryl azides and aldehydes.2,5-Diamide-Substituted Five-Membered Heterocycles: Challenging Molecular SynthonsA Quantum-Chemical DFT Approach to Elucidation of the Chirality Transfer Mechanism of the Enantioselective Suzuki–Miyaura Cross-Coupling Reaction
P2860
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P2860
A bulky biaryl phosphine ligand allows for palladium-catalyzed amidation of five-membered heterocycles as electrophiles
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
A bulky biaryl phosphine ligan ...... heterocycles as electrophiles
@ast
A bulky biaryl phosphine ligan ...... heterocycles as electrophiles
@en
type
label
A bulky biaryl phosphine ligan ...... heterocycles as electrophiles
@ast
A bulky biaryl phosphine ligan ...... heterocycles as electrophiles
@en
prefLabel
A bulky biaryl phosphine ligan ...... heterocycles as electrophiles
@ast
A bulky biaryl phosphine ligan ...... heterocycles as electrophiles
@en
P2860
P356
P1476
A bulky biaryl phosphine ligan ...... heterocycles as electrophiles
@en
P2093
Mingjuan Su
Stephen L Buchwald
P2860
P304
P356
10.1002/ANIE.201201244
P407
P577
2012-03-30T00:00:00Z