Metal-free α-amination of secondary amines: computational and experimental evidence for azaquinone methide and azomethine ylide intermediates.
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Redox-neutral α-sulfenylation of secondary amines: ring-fused N,S-acetals.Redox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism.The Rügheimer-Burrows reaction revisited: Facile preparation of 4-alkylisoquinolines and 3,5-dialkylpyridines from (partially) saturated aminesAsymmetric Redox-Annulation of Cyclic Amines.The azomethine ylide route to amine C-H functionalization: redox-versions of classic reactions and a pathway to new transformations.Redox-Annulation of Cyclic Amines and β-Ketoaldehydes.Hydrogen-Atom Transfer Reactions.Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core.Dual C-H functionalization of N-aryl amines: synthesis of polycyclic amines via an oxidative Povarov approach.The redox-Mannich reaction.The Redox-A(3) Reaction.Decarboxylative Annulation of α-Amino Acids with γ-Nitroaldehydes.Redox-neutral α,β-difunctionalization of cyclic amines.Redox-neutral α-C-H bond functionalization of secondary amines with concurrent C-P bond formation/N-alkylation.C-H functionalization of cyclic amines: redox-annulations with α,β-unsaturated carbonyl compounds.Redox-neutral α-arylation of amines.An Ugi Reaction Incorporating a Redox-Neutral Amine C-H Functionalization StepAcetic Acid Promoted Redox Annulations with Dual C-H Functionalization.Experimental and theoretical investigations into the stability of cyclic aminalsIntramolecular [3 + 2]-cycloadditions of azomethine ylides derived from secondary amines via redox-neutral C-H functionalization.Selective copper(II) acetate and potassium iodide catalyzed oxidation of aminals to dihydroquinazoline and quinazolinone alkaloids.Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C-H Functionalization.Direct N-H/α,α,β,β-C(sp3)-H functionalization of piperidine via an azomethine ylide route: synthesis of spirooxindoles bearing 3-substituted oxindoles.Classical-Reaction-Driven Stereo- and Regioselective C(sp(3) )-H Functionalization of Aliphatic Amines.Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization.Synthesis of Polycyclic Imidazolidinones via Amine Redox-Annulation.Regio- and Diastereoselective and Enantiospecific Metal-Free C(sp(3) )-H Arylation: Facile Access to Optically Active 5-Aryl 2,5-Disubstituted Pyrrolidines.
P2860
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P2860
Metal-free α-amination of secondary amines: computational and experimental evidence for azaquinone methide and azomethine ylide intermediates.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
2013年论文
@zh
2013年论文
@zh-cn
name
Metal-free α-amination of seco ...... zomethine ylide intermediates.
@en
type
label
Metal-free α-amination of seco ...... zomethine ylide intermediates.
@en
prefLabel
Metal-free α-amination of seco ...... zomethine ylide intermediates.
@en
P2093
P2860
P356
P1476
Metal-free α-amination of seco ...... zomethine ylide intermediates.
@en
P2093
Alena Yu Platonova
Arne Dieckmann
Chen Zhang
Daniel Seidel
Matthew T Richers
P2860
P304
P356
10.1021/JO400483H
P407
P50
P577
2013-04-02T00:00:00Z