Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles.
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Opportunities and challenges for direct C-H functionalization of piperazinesSolar synthesis: prospects in visible light photocatalysisRuthenium-Catalyzed Transfer Hydrogenation for C-C Bond Formation: Hydrohydroxyalkylation and Hydroaminoalkylation via Reactant Redox Pairs.Redox-neutral α-sulfenylation of secondary amines: ring-fused N,S-acetals.Visible light-induced oxidative coupling reaction: easy access to Mannich-type products.Redox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism.The Rügheimer-Burrows reaction revisited: Facile preparation of 4-alkylisoquinolines and 3,5-dialkylpyridines from (partially) saturated aminesAsymmetric Redox-Annulation of Cyclic Amines.Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights.C-H bond functionalization via hydride transfer: formation of α-arylated piperidines and 1,2,3,4-tetrahydroisoquinolines via stereoselective intramolecular amination of benzylic C-H bonds.Metal-free α-amination of secondary amines: computational and experimental evidence for azaquinone methide and azomethine ylide intermediates.Activation of sp3 C-H bonds with cobalt(I): catalytic synthesis of enamines.Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.Facile Access to Ring-Fused Aminals via Direct α-Amination of Secondary Amines with ortho-Aminobenzaldehydes. Synthesis of Vasicine, Deoxyvasicine, Deoxyvasicinone, Mackinazolinone and Ruteacarpine.Ruthenium-Catalyzed C-H Bond Activation Approach to Azolyl Aminals and Hemiaminal Ethers, Mechanistic Evaluations, and Isomer Interconversion.Synthesis and anticancer activity of all known (-)-agelastatin alkaloids.Direct Sp3α-C-H activation and functionalization of alcohol and ether.If C-H bonds could talk: selective C-H bond oxidationThe azomethine ylide route to amine C-H functionalization: redox-versions of classic reactions and a pathway to new transformations.A general strategy for organocatalytic activation of C-H bonds via photoredox catalysis: direct arylation of benzylic ethers.Redox-Annulation of Cyclic Amines and β-Ketoaldehydes.C-Alkylation by Hydrogen Autotransfer Reactions.Brønsted acid cocatalysts in photocatalytic radical addition of α-amino C-H bonds across Michael acceptors.Direct functionalization of (un)protected tetrahydroisoquinoline and isochroman under iron and copper catalysis: two metals, two mechanisms.Direct Acylation of C(sp(3))-H Bonds Enabled by Nickel and Photoredox Catalysis.Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core.Metal-free C(sp(3))-H functionalization: oxidative carbo-oxygenation of α-diazo carbonyls via radical dediazotization.α-Arylation of Saturated Azacycles and N-Methylamines via Palladium(II)-Catalyzed C(sp(3))-H Coupling.Dual C-H functionalization of N-aryl amines: synthesis of polycyclic amines via an oxidative Povarov approach.C-H functionalization of amines with aryl halides by nickel-photoredox catalysis.First selective direct mono-arylation of piperidines using ruthenium-catalyzed C-H activation.The redox-Mannich reaction.Redox-neutral α,β-difunctionalization of cyclic amines.Aryl Bromides and Aryl Chlorides for the Direct Arylation of Benzylic Amines Mediated by Ruthenium(II)Palladium-Catalyzed Directed C(sp(3))-H Arylation of Saturated Heterocycles at C-3 Using a Concise Optimization ApproachRemote Oxidation of Aliphatic C-H Bonds in Nitrogen-Containing Molecules.Vanadium-catalyzed oxidative Strecker reaction: α-C-H cyanation of para-methoxyphenyl (PMP)-protected primary amines.Redox-neutral α-C-H bond functionalization of secondary amines with concurrent C-P bond formation/N-alkylation.C-H functionalization of cyclic amines: redox-annulations with α,β-unsaturated carbonyl compounds.Tandem C-H oxidation/cyclization/rearrangement and its application to asymmetric syntheses of (-)-brussonol and (-)-przewalskine E.
P2860
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P2860
Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles.
@en
type
label
Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles.
@en
prefLabel
Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles.
@en
P356
P1476
Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles.
@en
P2093
Kevin R Campos
P304
P356
10.1039/B607547A
P577
2007-03-01T00:00:00Z