Metal-catalyzed [1,2]-alkyl shift in allenyl ketones: synthesis of multisubstituted furans.
about
An expedient route to substituted furans via olefin cross-metathesis.1,2-boryl migration empowers regiodivergent synthesis of borylated furans.Copper-, Silver-, and Gold-Catalyzed Migratory Cycloisomerizations Leading to Heterocyclic Five-Membered RingsCuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligandsOn the validity of Au-vinylidenes in the gold-catalyzed 1,2-migratory cycloisomerization of skipped propargylpyridines.Copper-catalyzed regioselective synthesis of furan via tandem cycloaddition of ketone with an unsaturated carboxylic acid under air.Synthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines.Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.Transition metal-mediated synthesis of monocyclic aromatic heterocyclesGold-catalyzed double migration-benzannulation cascade toward naphthalenes.Metal-catalyzed 1,2-shift of diverse migrating groups in allenyl systems as a new paradigm toward densely functionalized heterocycles.Multisubstituted N-fused heterocycles via transition metal-catalyzed cycloisomerization protocolsNew Approaches to the Synthesis of Metal Carbenes.Silver & gold-catalyzed routes to furans and benzofurans.Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: ligand-controlled regioselectivity.Computation-guided development of Au-catalyzed cycloisomerizations proceeding via 1,2-Si or 1,2-H migrations: regiodivergent synthesis of silylfurans.Gold(I)-catalyzed formation of furans from γ-acyloxyalkynyl ketones.Isotopic labelling studies for a gold-catalysed skeletal rearrangement of alkynyl aziridines.Tetrasubstituted allenes by Pd0-catalyzed three-component tandem Michael addition/cross-coupling reaction.Chemoselective synthesis of tetrasubstituted furans via intramolecular Wittig reactions: mechanism and theoretical analysis.Gold-catalyzed cyclization of 1-(indol-3-yl)-3-alkyn-1-ols: facile synthesis of diversified carbazoles.Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis.Copper/P(tBu)3 -Mediated Regiospecific Synthesis of Fused Furans and Naphthofurans.Synthesis of diversely substituted 2-(furan-3-yl)acetates from allenols through cascade carbonylations.Gold(I)-catalyzed regiodivergent rearrangements: 1,2- and 1,2'-alkyl migration in skipped alkynyl ketones.Palladium(II)-catalyzed stereospecific three-component domino reactions of diyne-enones, nucleophiles, and vinyl ketones.Gold(I)-catalyzed, highly diastereoselective, tandem heterocyclizations/[3+2] cycloadditions: synthesis of highly substituted cyclopenta[c]furans.Pd/Cu-catalyzed cascade Sonogashira coupling/cyclization reactions to highly substituted 3-formyl furans.Gold-catalyzed domino reactions consisting of regio- and stereoselective 1,2-alkyl migration.Facile synthesis of substituted 3-aminofurans through a tandem reaction of N-sulfonyl-1,2,3-triazoles with propargyl alcohols.A [3 + 2]-annulation approach to tetrasubstituted furans from MBH-carbonates of acetylenic aldehydes via sequential substitution/cycloisomerization.Acidic Co-Catalysts in Cationic Gold Catalysis.Mechanistic Understanding of the Divergent Cyclizations of o-Alkynylbenzaldehyde Acetals and Thioacetals Catalyzed by Metal Halides.An efficient synthesis of 2,5-diimino-furans via Pd-catalyzed cyclization of bromoacrylamides and isocyanides.
P2860
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P2860
Metal-catalyzed [1,2]-alkyl shift in allenyl ketones: synthesis of multisubstituted furans.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
Metal-catalyzed [1,2]-alkyl sh ...... is of multisubstituted furans.
@en
type
label
Metal-catalyzed [1,2]-alkyl sh ...... is of multisubstituted furans.
@en
prefLabel
Metal-catalyzed [1,2]-alkyl sh ...... is of multisubstituted furans.
@en
P2860
P356
P1476
Metal-catalyzed [1,2]-alkyl sh ...... sis of multisubstituted furans
@en
P2093
Vladimir Gevorgyan
P2860
P304
P356
10.1002/ANIE.200701128
P407
P577
2007-01-01T00:00:00Z