A novel 1,2-migration of acyloxy, phosphatyloxy, and sulfonyloxy groups in allenes: efficient synthesis of tri- and tetrasubstituted furans
about
1,2-boryl migration empowers regiodivergent synthesis of borylated furans.Copper-, Silver-, and Gold-Catalyzed Migratory Cycloisomerizations Leading to Heterocyclic Five-Membered RingsSynthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines.Stereocontrolled 1,3-phosphatyloxy and 1,3-halogen migration relay toward highly functionalized 1,3-dienes.Rh(I)-catalyzed cyclocarbonylation of allenol esters to prepare acetoxy 4-alkylidenecyclopent-3-en-2-ones.Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.Transition metal-mediated synthesis of monocyclic aromatic heterocyclesMechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: efficient synthesis of heterocycles via cascade migration/cycloisomerization approach.Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphatesMetal-catalyzed [1,2]-alkyl shift in allenyl ketones: synthesis of multisubstituted furans.Selective partial reduction of various heteroaromatic compounds with bridgehead nitrogen via Birch reduction protocol.Metal-catalyzed 1,2-shift of diverse migrating groups in allenyl systems as a new paradigm toward densely functionalized heterocycles.1,2-Halogen migration in haloallenyl ketones: regiodivergent synthesis of halofurans.Multisubstituted N-fused heterocycles via transition metal-catalyzed cycloisomerization protocolsGold(I)-catalyzed synthesis of (1E,3E)-dienes from propargylic esters.Silver and platinum-catalysed addition of O-H and N-H bonds to allenes.Silver & gold-catalyzed routes to furans and benzofurans.Computation-guided development of Au-catalyzed cycloisomerizations proceeding via 1,2-Si or 1,2-H migrations: regiodivergent synthesis of silylfurans.Rhodium-catalyzed carbonylation of cyclopropyl substituted propargyl esters: a tandem 1,3-acyloxy migration [5 + 1] cycloaddition.Heterocycles via intramolecular platinum-catalyzed propargylic substitution.Rhodium-catalyzed ring expansion of cyclopropanes to seven-membered rings by 1,5 C-C bond migration.Gold(I)-catalyzed formation of furans from γ-acyloxyalkynyl ketones.Electronic effects in the pt-catalyzed cycloisomerization of propargylic esters: synthesis of 2,3-disubstituted indolizines as a mechanistic probe.Complex alpha-pyrones synthesized by a gold-catalyzed coupling reaction.Synthesis of highly functionalized cyclohexenone rings: rhodium-catalyzed 1,3-acyloxy migration and subsequent [5+1] cycloaddition.Rhenium(I)-catalyzed cyclization of silyl enol ethers containing a propargyl carboxylate moiety: versatile access to highly substituted phenols.Silver-Catalyzed Isocyanide-Isocyanide [3+2] Cross-Cycloaddition Involving 1,2-Group Migration: Efficient Synthesis of Trisubstituted lmidazoles.Gold(I)-catalyzed regiodivergent rearrangements: 1,2- and 1,2'-alkyl migration in skipped alkynyl ketones.A [3 + 2]-annulation approach to tetrasubstituted furans from MBH-carbonates of acetylenic aldehydes via sequential substitution/cycloisomerization.
P2860
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P2860
A novel 1,2-migration of acyloxy, phosphatyloxy, and sulfonyloxy groups in allenes: efficient synthesis of tri- and tetrasubstituted furans
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年論文
@yue
2004年論文
@zh-hant
2004年論文
@zh-hk
2004年論文
@zh-mo
2004年論文
@zh-tw
2004年论文
@wuu
2004年论文
@zh
2004年论文
@zh-cn
name
A novel 1,2-migration of acylo ...... i- and tetrasubstituted furans
@en
A novel 1,2-migration of acylo ...... i- and tetrasubstituted furans
@nl
type
label
A novel 1,2-migration of acylo ...... i- and tetrasubstituted furans
@en
A novel 1,2-migration of acylo ...... i- and tetrasubstituted furans
@nl
prefLabel
A novel 1,2-migration of acylo ...... i- and tetrasubstituted furans
@en
A novel 1,2-migration of acylo ...... i- and tetrasubstituted furans
@nl
P2093
P2860
P356
P1476
A novel 1,2-migration of acylo ...... i- and tetrasubstituted furans
@en
P2093
Alexander V Kel'in
Anna W Sromek
Vladimir Gevorgyan
P2860
P304
P356
10.1002/ANIE.200353535
P407
P577
2004-04-01T00:00:00Z