Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
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Recent advances in copper-catalyzed asymmetric coupling reactionsAllylic functionalization of unactivated olefins with Grignard reagents.Regioselective and Diastereoselective Aminoarylation of 1,3-DienesEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsAlkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systemsEnantioselective CuH-Catalyzed Hydroallylation of Vinylarenes.Enantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids.On the Mechanism of Pd(0)-Catalyzed, Cu(I) Carboxylate-Mediated Thioorganic-Boronic Acid Desulfitative Coupling. A Non-innocent Role for Carboxylate Ligand.Mechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment.Asymmetric carbon-carbon bond formation gamma to a carbonyl group: phosphine-catalyzed addition of nitromethane to allenes.Copper-catalyzed divergent kinetic resolution of racemic allylic substrates.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Asymmetric conjugate additions and allylic alkylations using nucleophiles generated by hydro- or carbometallation.C-C bond formation via copper-catalyzed conjugate addition reactions to enones in water at room temperatureCopper-catalysed cross-coupling: an untapped potential.Diastereoselective and enantioselective conjugate addition reactions utilizing α,β-unsaturated amides and lactams.Facile Access to Fluoroaromatic Molecules by Transition-Metal-Free C-F Bond Cleavage of Polyfluoroarenes: An Efficient, Green, and Sustainable Protocol.Nucleophilic and Electrophilic Activation of Non-Heteroaromatic Amides in Atom-Economical Asymmetric Catalysis.Catalytic SN2'- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis.Enantioselective conjugate allylation of cyclic enonesChemistry. Copper's contribution to amination catalysis.Catalytic enantioselective addition of Grignard reagents to aromatic silyl ketimines.A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons.Enantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization.Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.Enantioselective assembly of tertiary stereocenters via multicomponent chemoselective cross-coupling of geminal chloro(iodo)alkanes.Carboxylic acids as a traceless activation group for conjugate additions: a three-step synthesis of (±)-pregabalin.Pd-catalyzed carbonylative conjugate addition of dialkylzinc reagents to unsaturated carbonyls.Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis.Enantioselective total synthesis of (-)-nardoaristolone B via a gold(I)-catalyzed oxidative cyclizationEnantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans.Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enonesLewis Acid Enabled Copper-Catalyzed Asymmetric Synthesis of Chiral β-Substituted Amides.Catalytic asymmetric synthesis of chiral allylic esters.Catalytic enantioselective conjugate allylation of unsaturated methylidene ketones.Asymmetric conjugate addition of oxindoles to 2-chloroacrylonitrile: a highly effective organocatalytic strategy for simultaneous construction of 1,3-nonadjacent stereocenters leading to chiral pyrroloindolines.A novel catalytic asymmetric route towards skipped dienes with a methyl-substituted central stereogenic carbon.Copper-free asymmetric allylic alkylation with a Grignard reagent: design of the ligand and mechanistic studies.
P2860
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P2860
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on August 2008
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
@en
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
@nl
type
label
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
@en
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
@nl
prefLabel
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
@en
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
@nl
P50
P356
P1433
P1476
Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.
@en
P2093
Koen Geurts
Syuzanna R Harutyunyan
P304
P356
10.1021/CR068424K
P577
2008-08-01T00:00:00Z