Ligand-controlled access to [4 + 2] and [4 + 3] cycloadditions in gold-catalyzed reactions of allene-dienes.
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A ligand-directed divergent catalytic approach to establish structural and functional scaffold diversity.Gold(I)-catalyzed enantioselective [4 + 2]-cycloaddition of allene-dienesGold-catalyzed Intermolecular [4C + 3C] Cycloaddition Reactions.A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.Development of catalysts and ligands for enantioselective gold catalysisGold(I)-catalyzed diastereo- and enantioselective 1,3-dipolar cycloaddition and Mannich reactions of azlactones.Recent advances in the gold-catalyzed additions to C-C multiple bonds.Meeting the challenge of intermolecular gold(I)-catalyzed cycloadditions of alkynes and allenesGold-catalyzed transannular [4+3] cycloaddition reactionsSynthesis of axially chiral gold complexes and their applications in asymmetric catalysesGold-catalyzed reaction of oxabicyclic alkenes with electron-deficient terminal alkynes to produce acrylate derivatives.Recent developments in gold-catalyzed cycloaddition reactions.Enantioselective, transition metal catalyzed cycloisomerizations.Gold(I)-catalyzed enantioselective cycloaddition reactions.[4+2] and [4+3] catalytic cycloadditions of allenes.Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition.Gold-Catalyzed Enantioselective Annulations.Thermal intramolecular [4 + 2] cycloadditions of allenamides: a stereoselective tandem propargyl amide isomerization-cycloaddition.Mechanistic study of gold(I)-catalyzed intermolecular hydroamination of allenes.On the impact of steric and electronic properties of ligands on gold(I)-catalyzed cycloaddition reactions.Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles.Access to the protoilludane core by gold-catalyzed allene-vinylcyclopropane cycloisomerization.Gold(I)-catalyzed domino cyclization for the synthesis of polyaromatic heterocycles.Mechanistic intricacies of gold-catalyzed intermolecular cycloadditions between allenamides and dienes.Chemoselective carbophilic addition of α-diazoesters through ligand-controlled gold catalysis.Gold(I)-catalyzed cascade cycloadditions between allenamides and carbonyl-tethered alkenes: an enantioselective approach to oxa-bridged medium-sized carbocycles.Gold(I)-catalyzed divergence in the preparation of bicyclic enol esters: from exclusively [3C+2C]-cycloaddition reactions to exclusive formation of vinylcyclopropanes.Diversity in Gold-Catalyzed Formal Cycloadditions of Ynamides with Azidoalkenes or 2H-Azirines: [3+2] versus [4+3] Cycloadditions.A combined NMR/DFT study on the ion pair structure of [(PR1(2)R2)Au(η2-3-hexyne)]BF4 complexes.Total Syntheses of the Reported Structures of Curcusones I and J through Tandem Gold Catalysis.Concise, Enantioselective, and Versatile Synthesis of (-)-Englerin A Based on a Platinum-Catalyzed [4C+3C] Cycloaddition of Allenedienes.A 11-Steps Total Synthesis of Magellanine through a Gold(I)-Catalyzed Dehydro Diels-Alder Reaction.Gold Catalysis-Facilitated Rapid Synthesis of the Daphnane/Tigliane Tricyclic Core.Access to divergent benzo-heterocycles via a catalyst-dependent strategy in the controllable cyclization of o-alkynyl-N-methoxyl-benzamides.Gold-catalyzed domino reactions consisting of regio- and stereoselective 1,2-alkyl migration.A gold(i)-catalyzed substituent-controlled cycloisomerization of propargyl vinyl ethers to multi-substituted furofuran and furopyran derivatives.Gold-catalyzed cycloisomerization of 1,6,8-dienyne carbonates and esters to cis-cyclohepta-4,8-diene-fused pyrrolidines.A gold-catalyzed 1,2-acyloxy migration/intramolecular cyclopropanation/ring enlargement cascade: syntheses of medium-sized heterocycles.Bis-phosphine allene ligand: coordination chemistry and preliminary applications in catalysis.Gold-Catalyzed Cyclization of Furan-Ynes bearing a Propargyl Carbonate Group: Intramolecular Diels-Alder Reaction with In Situ Generated Allenes.
P2860
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P2860
Ligand-controlled access to [4 + 2] and [4 + 3] cycloadditions in gold-catalyzed reactions of allene-dienes.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on May 2009
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Ligand-controlled access to [4 ...... ed reactions of allene-dienes.
@en
Ligand-controlled access to [4 ...... ed reactions of allene-dienes.
@nl
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label
Ligand-controlled access to [4 ...... ed reactions of allene-dienes.
@en
Ligand-controlled access to [4 ...... ed reactions of allene-dienes.
@nl
prefLabel
Ligand-controlled access to [4 ...... ed reactions of allene-dienes.
@en
Ligand-controlled access to [4 ...... ed reactions of allene-dienes.
@nl
P2860
P356
P1476
Ligand-controlled access to [4 ...... zed reactions of allene-dienes
@en
P2093
Ana Z González
Rachel M Zeldin
P2860
P304
P356
10.1021/JA901649S
P407
P577
2009-05-01T00:00:00Z