Catalytic asymmetric C-N bond formation: phosphine-catalyzed intra- and intermolecular γ-addition of nitrogen nucleophiles to allenoates and alkynoates
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1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysisThe ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Chiral phosphines in nucleophilic organocatalysisUse of a new spirophosphine to achieve catalytic enantioselective [4 + 1] annulations of amines with allenes to generate dihydropyrrolesPhosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives.Asymmetric cyanation of imines via dipeptide-derived organophosphine dual-reagent catalysis.Advances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs.Stereoselective Syntheses of α,β-Unsaturated γ-Amino Esters Through Phosphine-Catalyzed γ-Umpolung Additions of Sulfonamides to γ-Substituted Allenoates.Catalytic Enantioselective Carbon-Oxygen Bond Formation: Phosphine-Catalyzed Synthesis of Benzylic Ethers via the Oxidation of Benzylic C-H BondsPhosphine-Mediated Iterative Arene Homologation Using Allenes.Highly enantioselective, intermolecular hydroamination of allenyl esters catalyzed by bifunctional phosphinothioureas.Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings.An elimination/Heck coupling/allylation cascade reaction: synthesis of 2,3-dihydrobenzofurans from allenoate adducts.Amino acid derived phosphine-catalyzed enantioselective 1,4-dipolar spiroannulation of cyclobutenones and isatylidenemalononitrile.Phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides: expedient access to triarylmethanes.Phosphine-Catalyzed β,γ-Umpolung Domino Reaction of Allenic Esters: Facile Synthesis of Tetrahydrobenzofuranones Bearing a Chiral Tetrasubstituted Stereogenic Carbon Center.Enantioselective synthesis of 3-fluoro-3-allyl-oxindoles via phosphine-catalyzed asymmetric γ-addition of 3-fluoro-oxindoles to 2,3-butadienoates.Synergistic Lewis base and anion-binding catalysis for the enantioselective vinylogous addition of deconjugated butenolides to allenoates.Bridged [2.2.1] bicyclic phosphine oxide facilitates catalytic γ-umpolung addition-Wittig olefination.
P2860
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P2860
Catalytic asymmetric C-N bond formation: phosphine-catalyzed intra- and intermolecular γ-addition of nitrogen nucleophiles to allenoates and alkynoates
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 21 January 2013
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Catalytic asymmetric C-N bond ...... s to allenoates and alkynoates
@en
Catalytic asymmetric C-N bond ...... to allenoates and alkynoates.
@nl
type
label
Catalytic asymmetric C-N bond ...... s to allenoates and alkynoates
@en
Catalytic asymmetric C-N bond ...... to allenoates and alkynoates.
@nl
prefLabel
Catalytic asymmetric C-N bond ...... s to allenoates and alkynoates
@en
Catalytic asymmetric C-N bond ...... to allenoates and alkynoates.
@nl
P2093
P2860
P356
P1476
Catalytic asymmetric C-N bond ...... s to allenoates and alkynoates
@en
P2093
Ashraf Wilsily
Gregory C Fu
Nicolas Marion
Ying Kit Chung
P2860
P304
P356
10.1002/ANIE.201208957
P407
P577
2013-01-21T00:00:00Z