Use of a new spirophosphine to achieve catalytic enantioselective [4 + 1] annulations of amines with allenes to generate dihydropyrroles
about
Asymmetric copper-catalyzed C-N cross-couplings induced by visible lightAsymmetric cyanation of imines via dipeptide-derived organophosphine dual-reagent catalysis.Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric AnnulationsRapid Asymmetric Synthesis of Disubstituted Allenes by Coupling of Flow-Generated Diazo Compounds and Propargylated AminesEnantioselective Synthesis of Isoquinolines: Merging Chiral-Phosphine and Gold Catalysis.Catalyst-controlled regioselectivity in phosphine catalysis: the synthesis of spirocyclic benzofuranones via regiodivergent [3 + 2] annulations of aurones and an allenoate.Chiral phosphine-mediated intramolecular [3 + 2] annulation: enhanced enantioselectivity by achiral Brønsted acid.Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings.Enantioselective Phosphine-Catalyzed Formal [4+4] Annulation of α,β-Unsaturated Imines and Allene Ketones: Construction of Eight-Membered Rings.Engaging Allene-Derived Zwitterions in an Unprecedented Mode of Asymmetric [3+2]-Annulation Reaction.Access to thiopyrano[2,3-b]indole via tertiary amine-catalyzed formal (3+3) annulations of β'-acetoxy allenoates with indoline-2-thiones.Highly enantioselective synthesis of dihydrocoumarin-fused dihydropyrans via the phosphine-catalyzed [4 + 2] annulation of allenones with 3-aroylcoumarins.Phosphine-Catalyzed β,γ-Umpolung Domino Reaction of Allenic Esters: Facile Synthesis of Tetrahydrobenzofuranones Bearing a Chiral Tetrasubstituted Stereogenic Carbon Center.Stereodivergent Synthesis of N-Heterocycles by Catalyst-Controlled, Activity-Directed Tandem Annulation of Diazo Compounds with Amino Alkynes.Phosphine-catalyzed [5+1] annulation of δ-sulfonamido-substituted enones with N-sulfonylimines: a facile synthesis of tetrahydropyridines.Formal (4 + 1)-Addition of Allenoates to o-Quinone Methides.An unusual stereoretentive 1,3-quaternary carbon shift resulting in an enantioselective RhII-catalyzed formal [4+1]-cycloaddition between diazo compounds and vinyl ketenes.Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones.Rapid Asymmetric Synthesis of Disubstituted Allenes by Coupling of Flow-Generated Diazo Compounds and Propargylated Amines
P2860
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P2860
Use of a new spirophosphine to achieve catalytic enantioselective [4 + 1] annulations of amines with allenes to generate dihydropyrroles
description
2015 nî lūn-bûn
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2015年の論文
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2015年論文
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2015年論文
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2015年論文
@zh-hk
2015年論文
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2015年論文
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2015年论文
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2015年论文
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name
Use of a new spirophosphine to ...... es to generate dihydropyrroles
@ast
Use of a new spirophosphine to ...... es to generate dihydropyrroles
@en
type
label
Use of a new spirophosphine to ...... es to generate dihydropyrroles
@ast
Use of a new spirophosphine to ...... es to generate dihydropyrroles
@en
prefLabel
Use of a new spirophosphine to ...... es to generate dihydropyrroles
@ast
Use of a new spirophosphine to ...... es to generate dihydropyrroles
@en
P2860
P356
P1476
Use of a new spirophosphine to ...... es to generate dihydropyrroles
@en
P2093
Gregory C Fu
P2860
P304
P356
10.1021/JACS.5B01944
P407
P50
P577
2015-03-17T00:00:00Z